Non-adiabatic effect on NOx emissions for premixed H2-blended NH3/air combustion under rich-lean-staged conditions

被引：1

作者：

Li, Zhaoxing ^{[1
]}

Zhang, Yang ^{[1
]}

Zhang, Hai ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Energy & Power Engn, Key Lab Thermal Sci & Power Engn, Minist Educ, Beijing, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2024年 / 94卷

关键词：

Ammonia; NOx; Hydrogen blending; RQL combustion; Non-adiabatic; TURBINE-LIKE COMBUSTOR; LAMINAR BURNING VELOCITY; SWIRL FLAMES; AMMONIA; NH3/H-2/AIR; NH3/CO/AIR; EFFICIENT; HYDROGEN;

D O I：

10.1016/j.ijhydene.2024.11.164

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The non-adiabatic effect on NOx emission for the swirl premixed NH3/H2/air combustion under fuel-rich/quickmix/fuel-lean (RQL) conditions was experimentally studied. The wall temperature of the quartz combustor was controlled by surrounding heating. Results showed that both H2-blending and thermal insulation were in favor of enlarging the low-NOx range and lowering the valley NOx, due to the less NO and unburnt NH3, and smaller flow rate from the primary stage. In the post-flame zone of the primary stage, increasing combustion temperature significantly enhanced NO reduction, Thus, for low NOx emission, it is essential to keep enough thermal insulation there. Experimental measurements also found remarkable N2O could be formed in the secondary stage when combustion temperature was low and much unburnt NH3 was excessive. Kinetic analyses showed this phenomenon was due to the high combination rate of NH and NO, and low reduction rate of H radical.

引用

页码：934 / 942

页数：9

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