Study of impact factors on shale gas adsorption and desorption

被引:0
作者
Zhao, Yu-Ji [1 ]
Guo, Wei [2 ]
Xiong, Wei [2 ]
Zuo, Luo [2 ]
Gao, Shu-Sheng [2 ]
Liu, Hong-Lin [2 ]
Miao, Xue [3 ]
机构
[1] College of Geosciences and Surveying Engineering, China University of Mining and Technology
[2] Research Institute of Petroleum Exploration and Development-Langfang Branch
[3] Huabei Oilfield Exploration and Development Institute, PetroChina
关键词
Adsorption; Clay minerals; Moisture content; Shale gas; Temperature; TOC;
D O I
10.11764/j.issn.1672-1926.2014.06.0940
中图分类号
学科分类号
摘要
Adsorbed gas content is essential to the calculation of shale gas reserves, and adsorbed gas desorption process is directly related to the production of shale. Isothermal adsorption and desorption experiments under different conditions were carried out with Longmaxi shale samples collected from south of Sichuan and Zhaotong area. The results show that the maximum adsorption volume VL decreases with the increase of temperature and the desorption ratio increases with the increase of temperature, which both showed a good linear relationship with the temperature. TOC and clay mineral content will affect the shale gas adsorption capacity. The shale maximum adsorption volume has a positive correlation with TOC in shale with high TOC content, while the maximum adsorption volume and clay mineral content was positively correlated in shale with low TOC content. The presence of water will reduce the shale adsorption capacity and also the desorption ratio. The remaining adsorption volume after desorption increases with the moisture content.
引用
收藏
页码:940 / 946
页数:6
相关论文
共 24 条
[1]  
Zhang D., Main solution ways to speed up shale gas exploration and development in China, Natural Gas Industry, 31, 5, pp. 1-5, (2011)
[2]  
Huang C., The production of unconventional oil and gas of China is hopeful of getting to 100×10<sup>9</sup>m<sup>3</sup> in 2020, Petroleum Exploration and Development, 38, 5, (2011)
[3]  
Jia C., Zheng M., Zhang Y., Unconventional hydrocarbon resources in China and the prospect of exploration and development, Petroleum Exploration and Development, 39, 2, pp. 129-136, (2012)
[4]  
Wang F., He Z., Meng X., Et al., Occurrence of shale gas and prediction of original gas in place, Natural Gas Geoscience, 22, 3, pp. 501-510, (2011)
[5]  
Martini A.M., Walter L.M., Budai J.M., Et al., Genetic and temporal relations between formation waters and biogenic methane: Upper Devonian Antrim Shale, Michigan Basin, USA, Geochimica et Cosmochimica Acta, 62, 10, pp. 1699-1720, (1998)
[6]  
Daniel M.J., Ronald J.H., Tim E.R., Et al., Unconventional shale-gas systems: The Mississippian Barnett shale of north-central Texas as one model for thermogenic shale-gas assessment, AAPG Bulletin, 91, 4, pp. 475-499, (2007)
[7]  
Hill R.J., Zhang E., Katz B.J., Et al., Modeling of gas generation from the Barnett shale, Fort Worth basin, Texas, AAPG Bulletin, 91, 4, pp. 501-521, (2007)
[8]  
Ross D.J., Bustin R.M., Characterizing the shale gas resource potential of Devonian-Mississippian strata in the Western Canada sedimentary basin: Application of an integrated formation evaluation, AAPG Bulletin, 92, 1, pp. 87-125, (2008)
[9]  
Lu X.C., Li F.C., Watson A.T., Adsorption studies of natural gas storage in Devonian shales, SPE Formation Evaluation, 10, 2, pp. 109-113, (1995)
[10]  
Lu X.C., Li F.C., Watson A.T., Adsorption measurements in Devonian shales, Fuel, 74, 4, pp. 599-603, (1995)