Nonpolar (112¯0) a-plane gallium nitride thin films grown on (11¯02) r-plane sapphire: Heteroepitaxy and lateral overgrowth
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作者:
Craven, M.D.
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Materials Department, University of California, Santa Barbara, CA 93106, United StatesMaterials Department, University of California, Santa Barbara, CA 93106, United States
Craven, M.D.
[1
]
Lim, S.H.
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Materials Department, University of California, Santa Barbara, CA 93106, United StatesMaterials Department, University of California, Santa Barbara, CA 93106, United States
Lim, S.H.
[1
]
Wu, F.
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Materials Department, University of California, Santa Barbara, CA 93106, United StatesMaterials Department, University of California, Santa Barbara, CA 93106, United States
Wu, F.
[1
]
Speck, J.S.
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Materials Department, University of California, Santa Barbara, CA 93106, United StatesMaterials Department, University of California, Santa Barbara, CA 93106, United States
Speck, J.S.
[1
]
DenBaars, S.P.
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机构:
Materials Department, University of California, Santa Barbara, CA 93106, United StatesMaterials Department, University of California, Santa Barbara, CA 93106, United States
DenBaars, S.P.
[1
]
机构:
[1] Materials Department, University of California, Santa Barbara, CA 93106, United States
来源:
Physica Status Solidi (A) Applied Research
|
2002年
/
194卷
/
2 SPEC.期
关键词:
Atomic force microscopy - Electron diffraction - Epitaxial growth - Gallium nitride - Metallorganic chemical vapor deposition - Microstructure - Morphology - Nucleation - Sapphire - Substrates - Transmission electron microscopy - X ray diffraction analysis;
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摘要:
Nonpolar (112¯0) a-plane GaN films with planar surfaces were grown on (11¯02) r-plane sapphire substrates via metalorganic chemical vapor deposition by depositing a low temperature nucleation layer prior to the high temperature epitaxial growth. The film/substrate epitaxial relationship was defined by X-ray diffraction measurements to be [0001]GaN [1¯101]sapphire and [1¯100]GaN [112¯0]sapphire while the polarity of the GaN c-axis was confirmed using convergent beam electron diffraction. The film morphology and microstructure were studied using atomic force microscopy and transmission electron microscopy (TEM), respectively. Threading dislocations (TDs), which dominated the heteroepitaxial a-plane GaN microstructure (density ∼2.6 × 1010 cm-2), were reduced via lateral epitaxial overgrowth from mask stripe openings. The overgrowth from stripes aligned along [1¯100] was dislocation-free, as observed using TEM and cathodoluminescence, and dependent upon crystal polarity. For all other stripe orientations, TDs were observed to propagate into the overgrown regions.