Quantitative determination of PGM using ICP-MS, ICP-AES, AAS and XRF

被引：0
作者：
Yoon, H. [1 ]
Yoon, C. [1 ]
Park, C.S. [1 ]
Ko, T. [2 ]
Kim, N.S. [3 ]
Han, K.N. [3 ]
机构：
[1] Korea Basic Sci. Inst.-Seoul Branch, Seoul
[2] Department of Materials Science, Inha University, Inchon-si
[3] Dept. of Mat./Metallurgical Eng., South Dakota Sch. of Mines/Tech., Rapid City, SD
来源：
Minerals and Metallurgical Processing | 2005年 / 22卷 / 01期
关键词：
Atomic adsorption; Inductively coupled plasma; Platinum group metals; Quantitative analysis; X-ray fluorescence;
D O I：
10.1007/bf03403197
中图分类号：
学科分类号：
摘要：
The quantitative determination of platinum group metals from ore samples and industrial materials using inductively coupled plasma-mass spectrometer (ICP-MS), inductively coupled plasma-atomic emission spectrometer (ICP-AES), atomic absorption spectrometer (AAS) and X-ray fluorescence (XRF) techniques was conducted, and the performance of these techniques was compared. The ICP-AES technique exhibited better accuracy than AAS but showed limitations in its application due to strong spectral interference in the presence of common matrix elements such as iron. The ICP-MS showed the lowest detection limit and less spectral interference than the previous two techniques. The XRF technique was also applied to examine the total amount of PGM from industrial materials. Results from each analytical method on various sources were presented and discussed. Copyright 2005, Society for Mining, Metallurgy, and Exploration, Inc.
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页码：59 / 64
页数：5
相关论文
共 9 条
  • [1] Brefoot R.R., Determination of the precious metals in geological materials by inductively coupled plasma mass spectrometry, Journal, Anal. At. Spectrom., 13, pp. 1077-1084, (1998)
  • [2] Borisov O.V., Coleman D.M., Carter III R.O., Determination of vanadium, rhodium and platinum in automotive catalytic converters using Inductively Coupled Plasma Mass Spectrometry with Spark Ablation, Journal of Anal. Atom. Spectrometry, 12, pp. 231-237, (1997)
  • [3] Borisov O.V., Coleman D.M., Kristine A., Oudsema Carter III R.O., Determination of platinum, palladium, rhodium and titanium in automotive catalytic converters using Inductively Coupled Plasma Mass Spectrometry with liquid nebulization, Journal of Anal. Atom. Spectrometry, 12, pp. 239-246, (1997)
  • [4] Coedo A.G., Dorado M.T., Padilla I., Alguacil F., Preconcentration and matrix separation of precious metals in geological and related materials using metalfix-chelamie resin prior to inductively coupled plasma mass spectrometry, Analytica Chim. Acta., 340, pp. 31-40, (1996)
  • [5] Haines J., Robert R.V.D., The determination by atomic absorption spectrophotometry using electrothermal atomization of platinum, palladium, rhodium, ruthernium, and iridium, Counc. Miner. Technol. (MINTEK) Randburh, (1982)
  • [6] Hoffman E.L., Naldret A.J., Van Loon J.-L., The determination of the platinum group elements and gold in rocks and ores by neutron activation analysis after preconcentration by a nickel sulfide fire-assay technique on large samples, Anal. Chem. Acta., 109, pp. 159-166, (1978)
  • [7] Jarvis K.E., Williams J.G., Parry S.J., Bertalan E., Quantitative determination of the platinum-group elements and gold using NiS fire assay with laser ablation-inductively coupled plasma-mass spectrometry, Chem. Geology, 124, pp. 37-46, (1995)
  • [8] Jarvis I., Totland M.M., Jarvis K.E., Determination of the platinum group elements in geological materials by ICP-MS using microwave digestion, alkali fusion and cation-exchange chromatography, Chem. Geol., pp. 27-42, (1997)
  • [9] Vlasankova R., Otruba V., Bendl J., Fisera M., Kanicky V., Preconcentration of platinum group metals on modified silicagel and their determination by inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry in airborn particulates, Talanta, 48, pp. 839-846, (1999)
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