Research progress in synthesis, functionalization and metal adsorption of silica-based mesoporous materials

被引：0
|
作者：
Liu, Li [1 ,2 ]
Feng, Bo [1 ,2 ,3 ]
Wen, Yang [1 ,2 ]
Gu, Qixiong [1 ,2 ]
机构：
[1] Jiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Jiangxi University of Science and Technology, Jiangxi, Ganzhou
[2] School of Resources and Environment Engineering, Jiangxi University of Science and Technology, Jiangxi, Ganzhou
[3] Collaborative Innovation Center for Development, Utilization of Rare Metal Resources Co-sponsored by Ministry of Education and Jiangxi Province, Jiangxi University of Science and Technology, Jiangxi, Ganzhou
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2024年 / 43卷 / 09期
关键词：
adsorption; composites; mesoporous; silica; synthesis;
D O I：
10.16085/j.issn.1000-6613.2023-1424
中图分类号：
学科分类号：
摘要：
Silicon-based mesoporous materials are an emerging class of “milestone” materials with unique structure and properties such as tunable pore size, high specific surface area, ordered pore system and stable backbone for functionalization. So far, the application fields of these materials are still expanding, especially they have significant advantages in the adsorption of pollutants in wastewater and metal separation. Firstly, the research work of silicon-based mesoporous materials was briefly introduced, among which M41S and SBA series were the most widely studied. The preparation factors of silicon-based mesoporous materials, including template agent, silicon source, synthesis conditions and the effects of their interactions were reviewed. Material modification was inevitable. This paper summarized the research work of inorganic, organic and other modifications, and explained the function of functional modification on the structure and properties of materials. Finally, the application of these materials in metal adsorption and their adsorption properties and mechanisms were discussed, and the development direction of the synthesis and application of silicon-based mesoporous materials was prospected, which provided a theoretical basis for the reference in practical engineering. © 2024 Chemical Industry Press Co., Ltd.. All rights reserved.
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页码：5063 / 5078
页数：15
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  • [1] SALIMIAN S, ZADHOUSH A, MOHAMMADI A., A review on new mesostructured composite materials: Part Ⅰ . Synthesis of polymer-mesoporous silica nanocomposite, Journal of Reinforced Plastics and Composites, 37, 7, pp. 441-459, (2018)
  • [2] GUO Cheng, ZHANG Wei, TANG Yun, Ordered mesoporous materials: History, progress and perspective, Chemical Journal of Chinese Universities, 43, 8, pp. 25-41, (2022)
  • [3] KRESGE C T, LEONOWICZ M E, ROTH W J, Et al., Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism, Nature, 359, pp. 710-712, (1992)
  • [4] QIU Pengpeng, MA Bing, HUNG Chin-Te, Et al., Spherical mesoporous materials from single to multilevel architectures, Accounts of Chemical Research, 52, 10, pp. 2928-2938, (2019)
  • [5] ZHAO Dongyuan, HUO Qisheng, FENG Jianglin, Et al., Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures, Journal of the American Chemical Society, 120, 24, pp. 6024-6036, (1998)
  • [6] TIAN Bozhi, LIU Xiaoying, TU Bo, Et al., Self-adjusted synthesis of ordered stable mesoporous minerals by acid-base pairs, Nature Materials, 2, 3, pp. 159-163, (2003)
  • [7] SHI Yifeng, WAN Ying, TU Bo, Et al., Nanocasting synthesis of ordered mesoporous silicon nitrides with a high nitrogen content, The Journal of Physical Chemistry C, 112, 1, pp. 112-116, (2008)
  • [8] HOCHBAUM Allon I, GARGAS Daniel, HWANG Yun Jeong, Et al., Single crystalline mesoporous silicon nanowires, Nano Letters, 9, 10, pp. 3550-3554, (2009)
  • [9] ZHANG Renyuan, TU Bo, ZHAO Dongyuan, Synthesis of highly stable and crystalline mesoporous anatase by using a simple surfactant sulfuric acid carbonization method, Chemistry—A European Journal, 16, 33, pp. 9977-9981, (2010)
  • [10] TENG Zhaogang, SU Xiaodan, ZHENG Yuanyi, Et al., Mesoporous silica hollow spheres with ordered radial mesochannels by a spontaneous self-transformation approach, Chemistry of Materials, 25, 1, pp. 98-105, (2013)
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