Preparation and NTC characterization of Mn1.56Co0.96Ni0.48O4 nanopowders by solid-state ball milling hydrothermal method

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作者
Ma, Ren-Jun [1 ,2 ]
Chang, Ai-Min [1 ,2 ]
Gao, Bo [1 ,2 ]
Kong, Wen-Wen [1 ,2 ]
Xia, Jun-Bo [1 ,2 ]
机构
[1] Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry, Urumqi, China
[2] University of Chinese Academy of Sciences, Beijing, China
来源
关键词
The Mn1.56Co0.96Ni0.48O4 nanopowders were prepared by solid-state ball milling hydrothermal method. The effects of hydrothermal temperature on structure and morphology of the powders were studied and synthesis mechanism of solid-state ball milling hydrothermal method was discussed. The structure and electrical properties of the prepared samples were characterized by X-ray diffraction (XRD); Scanning electron microscope (SEM) and direct current (DC) resistance temperature measurement. Because it combines the advantages of the solid ball milling method and one-step hydrothermal method; the solid-state ball milling hydrothermal method can be applied to obtain smaller particle size and high dispersion of tetragonal spinel structure nanopowders at low crystallization temperatures. Electrical properties demonstrated that all ceramic samples prepared by the Mn1.56Co0.96Ni0.48O4 nanopowders have obviously negative temperature coefficient characteristics in a wide temperature range from 193K to 373 K. The B values were in the range of 3 396-3 625 K;
D O I
10.3969/j.issn.1001-9731.2014.20.031
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页码:20146 / 20149
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