Dehydration of 1,4-butanediol to tetrahydrofuran over La2P2W18O62/C catalyst

被引：0

作者：

Cao, Xiaohua ^{[1
,2
]}

Xu, Changlong ^{[1
]}

Wang, Xueyuan ^{[1
]}

Xie, Baohua ^{[1
]}

Yan, Ping ^{[1
,2
]}

机构：

[1] College of Chemistry and Environmental Engineering, Jiujiang University

[2] Jiangxi Province Research Center for Poyang Lake's Economy and Ecology

来源：

Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section) | 2014年 / 30卷 / 03期

关键词：

1; 4-butanediol; Catalytic activity; Dawson structure; Tetrahydrofuran;

D O I：

10.3969/j.issn.1001-8719.2014.03.008

中图分类号：

学科分类号：

摘要：

The catalyst of lanthanum phosphotungstate with Dawson structure supported on activated carbon (La2P2W18O62/C) was prepared by impregnation method and characterized by FT-IR, XRD, SEM and TG. The catalytic performance was studied in the catalytic synthesis of tetrahydrofuran from 1, 4-butanediol.The effects of catalyst dosage, reaction time, reaction temperature and repeated times of catalyst on the yield of tetrahydrofuran were investigated. The results showed that under the optimal conditions, i.e., w(Catalyst) = 3.9%(Relative to the dosage of 1, 4-butanediol), reaction temperature of 185°C and reaction time of 40 min, the yield of tetrahydrofuran reached 94.9%. The activity of La2P2W18O62/C catalyst remained basically unchanged after five runs and the yield of tetrahydrofuran was still above 91.3%.

引用

页码：428 / 433

页数：5

共 18 条

[1] (2003)
[2] Zhou Z., Discuss the market value and production technology of tetrahydrofuran, China Chemical Trade, 11, (2012)
[3] Cao X., Ren J., Liu M., Et al., Dehydration of 1,4-butanediol to tetrahydrofuran catalyzed by H6P2W18O62/Diatomite, Chinese Journal of Organic Chemistry, 33, 5, pp. 1035-1041, (2013)
[4] Cao X., Ren J., Xu C., Et al., Preparation, characterization and catalytic application of H6P2 W18O62/SiO2 for the synthesis of tetrahydrofuran, Journal of Jiangsu University(Natural Science Edition), 34, 3, pp. 25-30, (2013)
[5] Cao X., Yan P., Xie B., Et al., Dehydration of 1, 4-butanediol to tetrahydrofuran catalyzed by H9P2W15V3/C, Chemical Industry and Engineering Progress, 31, 5, pp. 1126-1129, (2012)
[6] Xie B., Cao X., Tian X., Et al., Synthesis of tetrahydrofuran on phosphotungstic acid/multiwalled carbon nanotube catalyst with Dawson structure, Petrochemical Technology, 37, 12, pp. 1299-1303, (2008)
[7] Li S., Li X., Cao X., Synthesis of tetrahydrofuran by using phosphotungstic acid with Dawson structure, China Tungsten Industry, 22, 4, pp. 36-38, (2007)
[8] Wu H., Zhou M., Qu Y., Et al., Preparation and characterization of tungstensubstituted molybdophosphoric acids and catalytic cyclodehydration of 1, 4-butanediol to tetrahydrofuran, Chinese Journal of Chemical Engineering, 17, 2, pp. 200-206, (2009)
[9] Aghaziarati M., Kazemeini M., Soltanieh M., Et al., Evaluation of zeolites in production of tetrahydrofuran from 1,4-butanediol: Performance tests and kinetic investigations, Industrial and Engineering Chemistry Research, 46, 3, pp. 726-733, (2007)
[10] Heravi M.M., Sadjadi S., Recent developments in use of heteropolyacids, their salts and polyoxometalates in organic synthesis, Journal of the Iranian Chemical Society, 6, 1, pp. 1-54, (2009)

← 1 2 →