Higher Stability of Soil Organic Matter near the Permafrost Table in a Peatland of Northeast China

Understanding the stability of soil organic matter (SOM) is essential for making accurate predictions regarding carbon release rates. However, there is limited information on the role of chemical composition of dissolved organic matter (DOM) in SOM stability. To address this gap, the peatland soil profile in the discontinuous frozen soil region of Northeast China was selected as the focus of this research, and a comprehensive analysis was conducted on the differences between the molecular composition of DOM and the stability of SOM. The results indicate a significant carbon accumulation phenomenon near the permafrost table. Through analyses using TG-50, delta 13C, and delta 15N, it was determined that SOM near the permafrost table exhibits high stability, whereas SOM within the permafrost layer demonstrates poor stability. Investigations utilizing UV-vis, 3D-EEM, FT-IR, and 1H-NMR technologies revealed that DOM near the permafrost table is of high quality and highly aromatic. Furthermore, compared to near the permafrost table, humic acid materials in the permafrost layer decreased by 17%, while protein materials increased by 17%. These findings offer a novel perspective on the understanding of SOM stability in peatland soil profiles within discontinuous permafrost regions.