Crosslinking copolymerization of N-vinylformamide in inverse suspension

被引:0
|
作者
Jagiellonian University, Department of Chemistry, Ul. R. Ingardena 3, 30-060 Kraków, Poland [1 ]
机构
[1] Jagiellonian University, Department of Chemistry, 30-060 Kraków
来源
Polimery/Polymers | 2008年 / 53卷 / 06期
关键词
Anion-exchangers; N-vinylformamide; Polyvinylamine; Suspension polymerization;
D O I
10.14314/polimery.2008.477
中图分类号
学科分类号
摘要
Crosslinking copolymerization of N-vinylformamide (NVF) and divinylbenzene (DVB) has been carried out in reverse suspension in presence of water which serves as porosity generating feature (porogene). The continuous phase was provided by silicone oil or paraffin oil. In silicone oil the copolymer resulted in form of regular spheres what was not the case when paraffin oil was used. After base hydrolysis anion-exchangers were obtained having primary amine groups attached to the backbone. Exchange capacity, degree of swelling, water content in air conditioned resin and the specific surface were determined.
引用
收藏
页码:477 / 480
页数:3
相关论文
共 50 条
  • [1] Crosslinking copolymerization of N-vinylformamide in inverse suspension
    Witek, Ewa
    POLIMERY, 2008, 53 (06) : 477 - 480
  • [2] Aqueous-Phase Copolymerization of N-Vinylpyrrolidone and N-Vinylformamide
    Santanakrishnan, Sandhya
    Stach, Marek
    Lacik, Igor
    Hutchinson, Robin A.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2012, 213 (13) : 1330 - 1338
  • [3] On some aspects concerning solution-suspension polymerization of N-vinylformamide
    Witek, Ewa
    Bortel, Edgar
    Gawelek, Katarzyna
    POLIMERY, 2013, 58 (01) : 14 - 17
  • [4] Synthesis of a thermosensitive polycation by random copolymerization of N-vinylformamide and N-vinylbutyramide
    Tachaboonyakiat, Wanpen
    Ajiro, Hiroharu
    Akashi, Mitsuru
    POLYMER JOURNAL, 2013, 45 (09) : 971 - 978
  • [5] On some aspects concerning solution-suspension polymerization of n-vinylformamide
    Witek, E. (witek@chemia.uj.edu.pl), 1600, Industrial Chemistry Research Institute (58): : 14 - 17
  • [6] Radical Copolymerization of N-Vinylformamide with Methylvinylketone: An Approach to Iminium/Imine Ring Containing Polymers
    Walther, Tina
    Seifert, Andreas
    Haehnle, Hans-Joachim
    Hamers, Christoph
    Spange, Stefan
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2019, 220 (02)
  • [7] Acidic and basic hydrolysis of poly(N-vinylformamide)
    Gu, L
    Zhu, S
    Hrymak, AN
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 86 (13) : 3412 - 3419
  • [8] Mechanism for base hydrolysis of poly(N-vinylformamide)
    Witek, Ewa
    Pazdro, Marcin
    Bortel, Edgar
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2007, 44 (4-6): : 503 - 507
  • [9] KINETIC FEATURES OF HOMOPOLYMERIZATION OF N-VINYLFORMAMIDE (IN WATER AND IN BULK)
    Nesterova, N. A.
    Panarin, E. F.
    Gavrilova, I. I.
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2014, 57 (03): : 16 - +
  • [10] Kinetics and modeling of free radical polymerization of N-vinylformamide
    Gu, L
    Zhu, S
    Hrymak, AN
    Pelton, RH
    POLYMER, 2001, 42 (07) : 3077 - 3086