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In Situ Fabrication of Hierarchically Branched TiO2 Nanostructures: Enhanced Performance in Photocatalytic H2 Evolution and Li-Ion Batteries
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作者:

Yang, Guorui
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Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China
Natl Univ Singapore, Dept Mech Engn, Singapore 117574, Singapore Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China

Wang, Ling
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Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China

Peng, Shengjie
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Natl Univ Singapore, Dept Mech Engn, Singapore 117574, Singapore
Nanjing Univ Aeronaut & Astronaut, Jiangsu Key Lab Mat & Technol Energy Convers, Coll Mat Sci & Technol, Nanjing 210016, Jiangsu, Peoples R China Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China

Wang, Jianan
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Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China

Ji, Dongxiao
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Natl Univ Singapore, Dept Mech Engn, Singapore 117574, Singapore Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China

Yan, Wei
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Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China

Ramakrishna, Seeram
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Natl Univ Singapore, Dept Mech Engn, Singapore 117574, Singapore Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China
机构:
[1] Xi An Jiao Tong Univ, Dept Environm Sci & Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China
[2] Natl Univ Singapore, Dept Mech Engn, Singapore 117574, Singapore
[3] Nanjing Univ Aeronaut & Astronaut, Jiangsu Key Lab Mat & Technol Energy Convers, Coll Mat Sci & Technol, Nanjing 210016, Jiangsu, Peoples R China
来源:
基金:
中国博士后科学基金;
关键词:
branched;
electrospinning;
H-2;
in situ growth;
Li-ion batteries;
ELECTROCHEMICAL PERFORMANCE;
FACILE SYNTHESIS;
NANOFIBERS;
ELECTRODES;
ARRAYS;
INTERCALATION;
PHOTOCURRENT;
COMPOSITES;
NANOTUBES;
NANOWIRES;
D O I:
10.1002/smll.201702449
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
1D branched TiO2 nanomaterials play a significant role in efficient photocatalysis and high-performance lithium ion batteries. In contrast to the typical methods which generally have to employ epitaxial growth, the direct in situ growth of hierarchically branched TiO2 nanofibers by a combination of the electrospinning technique and the alkali-hydrothermal process is presented in this work. Such the branched nanofibers exhibit improvement in terms of photocatalytic hydrogen evolution (0.41 mmol g(-1) h(-1)), in comparison to the conventional TiO2 nanofibers (0.11 mmol g(-1) h(-1)) and P25 (0.082 mmol g(-1) h(-1)). Furthermore, these nanofibers also deliver higher lithium specific capacity at different current densities, and the specific capacity at the rate of 2 C is as high as 201. 0 mAh g(-1), roughly two times higher than that of the pristine TiO2 nanofibers.
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