Laser power modulation between disturbed and undisturbed material removal regime in laser chemical processing

Laser chemical machining (LCM) is a method for removing material by thermally induced chemical dissolution of self-passivating metals. However, the process window is limited by disrupted material removal due to gas bubble formation and metallic salts and oxides deposition at higher energy input. Since the temperature increases, and therefore gas bubble growth takes time, it is hypothesized that the temporal modulation of laser power can remove the metal homogeneously, i.e., without disrupted material removal, while achieving a higher removal rate. Based on this, the dynamic process behavior of material removal is investigated for the LCM of titanium in phosphoric acid, using a rectangular modulation of the laser power with varying irradiation durations. As a result, however, high-speed videos show that gas bubbles are consistently generated, regardless of the applied laser power and power modulation, although the quantity of bubbles varies with different parameters. Even with short power durations (10 ms), the material deposition occurs after multiple irradiations. When the duration is longer, the material deposition increases in height along the laser scan direction. For the studied process parameters, a Fourier analysis in the spatial domain further indicates the correlation between the material removal frequencies and the modulation frequencies. In conclusion, the laser power modulation cannot prevent the disturbed material removal at high laser powers. Nevertheless, the material deposition can be utilized to generate periodic surface structures with a depth below and above the initial surface.