Spatiotemporal Variations and Characteristics of CO, H2CO and HCN Emissions from Biomass Burning Monitored by FTIR Spectroscopy

Studies of the impact of biomass burning and the emissions of trace gases from biomass burning, especially using long-term observations, are scarce in China. We utilize solar absorption spectra obtained via ground-based high-resolution Fourier transform infrared (FTIR) spectroscopy to retrieve the atmospheric total columns and vertical profiles of carbon monoxide (CO), formaldehyde (H2CO), and hydrogen cyanide (HCN) in Hefei, China. Seasonal and interannual variability in the three gases from 2016 to 2022 are analyzed. Atmospheric CO shows significant seasonal variations, peaking during spring and winter, and declining during summer, with a seasonal amplitude of 8.07 x 10(17) molecules cm(-2) and a seasonal variability of 29.35%. H2CO and HCN have similar seasonal patterns to each other, with high concentrations in summer and low concentrations in winter. The seasonal amplitude of H2CO and HCN are 1.89 x 10(16) molecules cm(-2) and 2.32 x 10(15) molecules cm(-2), respectively, with a seasonal variability of 133.07% and 34.69%, respectively. The means of the annual variation rate for CO, H2CO, and HCN are (-2.67 +/- 2.88)% yr(-1), (2.52 +/- 12.48)% yr(-1) and (-3.48 +/- 7.26)% yr(-1), respectively. To assess the influence of biomass burning on the variations in column concentrations of the three gases, the correlation between CO, H2CO, and HCN was analyzed. The months during which the monthly correlation coefficient between CO and H2CO with HCN exceeds 0.8, and the fire radiative power (FRP) observed by satellites is larger than its monthly average are regarded as a biomass-burning occurrence in Anhui province. Additionally, the enhancement ratios of Delta H2CO/Delta CO and Delta HCN/Delta CO were calculated for the periods impacted by the biomass burning. Finally, backward trajectory cluster analysis and the potential source contribution function (PSCF) calculation identified the air mass transport pathways and the potential source areas at the Hefei site.