Surface grafting modification of silicone rubber and its bacteriostatic properties

被引:0
作者
Qu P. [1 ]
Jiang Y. [1 ,2 ,3 ]
Sun X. [1 ]
Zhang H.-W. [1 ]
机构
[1] School of Materials Science and Engineering, Changzhou University, Changzhou
[2] College of Chemical Engineering, Nanjing Forestry University, Nanjing
[3] Jiangsu Chenguang Paint Co. Ltd., Changzhou
来源
Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities | 2016年 / 30卷 / 01期
关键词
Bacterial adhesion; Biocompatibility; Room temperature vulcanized silicone rubber (RTV-SR); Surface modification;
D O I
10.3969/j.issn.1003-9015.2016.01.035
中图分类号
学科分类号
摘要
Room Temperature Vulcanized Silicone Rubber (RTV-SR) was prepared using a composite cross-linking agent. Active groups were introduced onto silicone rubber surface by plasma, and poly(acrylamide)(PAM) was then grafted via surface-initiated atom transfer radical polymerization. The structure, composition, morphology and properties of the modified SR film were characterized by Fourier Transform Infrared Spectrometry (FT-IR/ATR), Contact Angle, XPS, and SEM before and after modification. The bacterial modified silicone rubber was studied by bacterial adhesion on the adhesion experiment. The water contact angle of the SR film decreased from 108.5° to 49.5° after grafting with PAM. The bacterial adhesion experiment data show that the surface structure and performance of SR have a great effect on bacterial adhesion. Compared with raw SR, the amount of bacterial adhesion decreased by 98.7% on the SR film grafted with PAM. © 2016, Zhejiang University. All right reserved.
引用
收藏
页码:234 / 239
页数:5
相关论文
共 15 条
  • [1] Xie Z.-H., Zeng F.-W., Xiao J.-B., Performance and progress of silicone rubber, Special Rubber Products, 32, 2, pp. 69-72, (2011)
  • [2] Whitesides G.M., The origins and the future of microfluidics, Nature, 442, 7101, pp. 368-373, (2006)
  • [3] Zhu C.-F., Li B.-G., Yao M., Et al., Characterization of coloring structure unit of polysiloxane modified polyurethane latex, J Chem Eng of Chinese Univ, 21, 1, pp. 127-129, (2007)
  • [4] Kang J., Application and modification technology of Silicone rubber, Rubber Technology Market, 13, pp. 12-14, (2008)
  • [5] Zhang C.-Y., Silicone rubber applications in the biomedical field, Silicone Materials, 16, 6, pp. 14-17, (2002)
  • [6] Xu M., Zhao Y.-Q., Li H.-M., The study about the anti-bacterial adhesion ability of medical silicone rubber grafted by ultraviolet hydrophilic modification, Science Technology and Engineering, 28, 14, pp. 265-268, (2014)
  • [7] Fundeanua I., Kleeb D., Schouten A.J., Et al., Solvent-free functionalization of silicone rubber and efficacy of PAAm brushes grafted from an amino-PPX layer against bacterial adhesion, Acta Biomaterialia, 11, 6, pp. 4271-4276, (2010)
  • [8] Wang L., Chen H., Song W., Research progress of silicone elastomer surface biocompatibility, Polymer Bulletin, 10, pp. 21-25, (2007)
  • [9] Chen X.-D., Pu D.-X., Plasma surface hydrophilic modification of silicone rubber, Polymer Materials Science & Engineering, 16, 1, pp. 153-155, (2000)
  • [10] Li W., Yao S.-Y., Ma K.-M., Et al., Study on the application of plasma modification to carbon fiber/PEK-C composites, J Chem Eng of Chinese Univ, 28, 3, pp. 690-694, (2014)