A global reference for black shale geochemistry and the T-OAE revisited: upper Pliensbachian - middle Toarcian (Lower Jurassic) chemostratigraphy in the Cleveland Basin, England

The Pliensbachian-Toarcian succession of North Yorkshire provides a global reference for the interval incorporating the Toarcian Oceanic Anoxic Event (T-OAE, similar to 183 Ma). Major and trace element, carbon stable-isotope (delta C-13(org)) and total organic carbon (TOC) data for the Dove's Nest core, drilled close to the classic outcrop sections of the Yorkshire coast, demonstrate geochemical, mineralogical and grain-size trends linked to sea level and climate change in the Cleveland Basin. High-resolution correlation between the core and outcrop enables the integration of data to generate a comprehensive chemostratigraphic record. Palaeoredox proxies (Mo, U, V, TOC/P, DOP and Fe speciation) show a progressive shift from oxic bottom waters in the late Pliensbachian through dysoxic-anoxic conditions in the earliest Toarcian to euxinia during the T-OAE. Anoxia-dysoxia persisted into the middle Toarcian. Elemental and isotope data (Re, Re/Mo, delta S-34(CAS), delta Mo-98 and epsilon Tl-205) from the coastal sections evidence global expansion of anoxic and euxinic seafloor area driving drawdown of redox-sensitive metals and sulfate from seawater leading to severe depletion in early Toarcian ocean water. The record of anoxia-euxinia in the Cleveland Basin largely reflects global-scale changes in ocean oxygenation, although metal depletion was temporarily enhanced by periods of local basin restriction. Osmium and Sr isotopes demonstrate a pulse of accelerated weathering accompanying the early Toarcian hyperthermal, coincident with the T-OAE. The combined core and outcrop records evidence local and global environmental change accompanying one of the largest perturbations in the global carbon cycle during the last 200 Ma and a period of major biotic turnover.