Syntheses of novel metal hydrides under high pressure and high temperature

被引：0
作者：
Saitoh H. [1 ]
Takagi S. [2 ]
Orimo S.-I. [2 ,3 ]
Aoki K. [4 ]
机构：
[1] Quantumn Beam Science Center, Japan Atomic Energy Agency, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo
[2] Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan.
[3] WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai
[4] School of Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo
来源：
Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy | 2016年 / 63卷 / 05期
关键词：
High pressure and high temperature; Hydride; In situ x-ray diffraction measurement;
D O I：
10.2497/jjspm.63.298
中图分类号：
学科分类号：
摘要：
Novel hydrides are synthesized under high pressure and high temperature, where novel hydrogenation reactions are expected to be realized owing to high reactivity of hydrogen fluid. Theoretical calculations predict stabilities of hydrides before experiments, of which results are effectively used for the synthetic studies. In situ synchrotron radiation x-ray diffraction measurement enables us to explore reaction conditions and to reveal the reaction mechanism. In the present paper, synthetic studies of Al2CuH and Li4FeH6 will be presented along with the experimental details.
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页码：298 / 305
页数：7
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