MnCo2O4 nanospheres entrapped in g-C3N4 network for High-Performance supercapacitor applications

被引:6
作者
Naresh, B. [1 ]
Sreekanth, T. V. M. [2 ]
Yoo, K. [2 ]
Kim, J. [1 ]
机构
[1] Chungnam Natl Univ, Dept Elect Engn, Energy Storage Convers Lab, Daejeon 34134, South Korea
[2] Yeungnam Univ, Sch Mech Engn, Gyongsan 38541, South Korea
关键词
Solvothermal; Nanospheres; g-C3N4/MnCo2O4; Supercapacitors; ELECTROCHEMICAL PERFORMANCE; NANOSHEETS; NICO2O4;
D O I
10.1016/j.matlet.2024.137520
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
MnCo2O4 2 O 4 nanospheres were embedded in a g-C3N4 3 N 4 network using the solvothermal method with ethylene glycol as the solvent. SEM confirmed the uniformity of the MnCo2O4/g-C3N4 2 O 4 /g-C 3 N 4 nanospheres, while XRD and XPS were used for structural and elemental analysis, including metal oxidation states. BET analysis revealed the surface area and porosity, while TEM analysis provided information on the interplanar spacing and morphology. Electrochemical evaluations using CV, GCD, and EIS demonstrated that the 2D g-C3N4 3 N 4 nanosheets interwoven with MnCo2O4 2 O 4 nanospheres have excellent specific capacities (654 Fg-- 1 at 2 Ag-1)- 1 ) and power densities (1521.2 W/kg at 7 Ag-- 1 ). The electrode material shows superior cyclic stability with 92.3 % capacitance retention after 5000 cycles.
引用
收藏
页数:4
相关论文
共 14 条
[1]   Manganese-, cobalt-, and zinc-based mixed-oxide spinels as novel catalysts for the chemical recycling of poly(ethylene terephthalate) via glycolysis [J].
Imran, Muhammad ;
Kim, Do Hyun ;
Al-Masry, Waheed A. ;
Mahmood, Asif ;
Hassan, Azman ;
Haider, Sajjad ;
Ramay, Shahid M. .
POLYMER DEGRADATION AND STABILITY, 2013, 98 (04) :904-915
[2]   High-performance self-assembly MnCo2O4 nanosheets for asymmetric supercapacitors [J].
Li, Jianwei ;
Xiong, Dongbin ;
Wang, Linzhe ;
Hirbod, Maleki Kheimeh Sari ;
Li, Xifei .
JOURNAL OF ENERGY CHEMISTRY, 2019, 37 :66-72
[3]   Hollow structured and flower-like C@MnCo2O4 composite for high electrochemical performance in a supercapacitor [J].
Li, Lei ;
He, Fei ;
Gai, Shili ;
Zhang, Shenghuan ;
Gao, Peng ;
Zhang, Milin ;
Chen, Yujin ;
Yang, Piaoping .
CRYSTENGCOMM, 2014, 16 (42) :9873-9881
[4]   The synergistic effect of carbon nanotubes and graphitic carbon nitride on the enhanced supercapacitor performance of cobalt diselenide-based composites [J].
Li, Mingjie ;
Zheng, Xuan ;
Xie, Lixiang ;
Yu, Youjun ;
Jiang, Jinlong .
NEW JOURNAL OF CHEMISTRY, 2021, 45 (32) :14808-14814
[5]   Recent progress on biomass waste derived activated carbon electrode materials for supercapacitors applications-A review [J].
Manasa, Pantrangi ;
Sambasivam, Sangaraju ;
Ran, Fen .
JOURNAL OF ENERGY STORAGE, 2022, 54
[6]   Biomass Waste Derived Low Cost Activated Carbon from Carchorus Olitorius (Jute Fiber) as Sustainable and Novel Electrode Material [J].
Manasa, Pantrangi ;
Lei, Zhang Jun ;
Ran, Fen .
JOURNAL OF ENERGY STORAGE, 2020, 30
[7]   Characterization of the nickel cobaltite, NiCo2O4 prepared by several methods:: An XRD, XANES, EXAFS, and XPS study [J].
Marco, JF ;
Gancedo, JR ;
Gracia, M ;
Gautier, JL ;
Ríos, E ;
Berry, FJ .
JOURNAL OF SOLID STATE CHEMISTRY, 2000, 153 (01) :74-81
[8]   Large-scale synthesis of porous NiCo2O4 and rGO-NiCo2O4 hollow-spheres with superior electrochemical performance as a faradaic electrode [J].
Mondal, Aniruddha ;
Maiti, Sandipan ;
Mahanty, Sourindra ;
Panda, Asit Baran .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (32) :16854-16864
[9]   Solvothermal synthesis of MnCo2O4 microspheres for high-performance electrochemical supercapacitors [J].
Naresh, Bodicherla ;
Kuchi, Charan ;
Rajasekhar, D. ;
Reddy, P. Sreedhara .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2022, 640
[10]  
Saravanakumar B., 2019, Mater. Sci. Energy Technol, V2, P130, DOI [10.1016/j.mset.2018.11.008, DOI 10.1016/J.MSET.2018.11.008]