Synthesis of Mn(III) phosphates

被引:0
作者
Nagornyj, P.G. [1 ]
Lavrik, R.V. [1 ]
Petrenko, O.V. [1 ]
机构
[1] Kievskij Natsional'nyj Univ., Kiev, Ukraine
来源
Ukrainskij Khimicheskij Zhurnal | 2002年 / 68卷 / 7-8期
关键词
Alkali metal compounds - Crystal growth from melt - Crystallization - Manganese compounds - Molten materials - Nitrates;
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摘要
A possibility of forming simple and complex phosphates containing Mn(III) was shown by the methods of solid-phase synthesis, the interaction of Mn(II) metaphosphate in molten alkali metal nitrates and spontaneous crystallization from phosphate melts with Mn(II) oxide and an alkali metal nitrate. MMnP2O7 (M = Li, Na, and K) double diphosphates, as well as Na2Mn2O(PO4)2 and Na2MnP2O7 double phosphates were synthesized and their physicochemical properties were studied.
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页码:25 / 27
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