Solid-State Reversible Phase Transition and Photoluminescence Properties of Organic-Inorganic Hybrid Halide: (BTPA)2MnBr4

被引：1

作者：

Yu, Xincheng ^{[1
]}

Liu, Yao ^{[2
]}

Liu, Yiyuan ^{[1
]}

Li, Shengkai ^{[2
]}

Tan, Haibin ^{[2
]}

Liu, Jinzhen ^{[2
]}

Chen, Zhiguo ^{[1
]}

机构：

[1] Chibi Yuntian New Mat Technol Co Ltd, Xianning 437300, Hubei, Peoples R China

[2] Gannan Univ Sci & Technol, Coll Rare Earth & New Mat Engn, Ganzhou Key Lab Adv Proc & Technol Optimizat High, Ganzhou 341000, Jiangxi, Peoples R China

来源：

INORGANIC CHEMISTRY | 2024年 / 63卷 / 46期

关键词：

DIELECTRIC RESPONSES; PEROVSKITES; PROGRESS;

D O I：

10.1021/acs.inorgchem.4c02359

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Multifunctional materials have long been a popular research area, with organic-inorganic hybrids frequently utilized due to their diverse properties and versatile assembly techniques. In this context, a novel Mn-based organic-inorganic hybrid compound (BTPA)2MnBr4(1) was prepared, with strong green photoluminescence, phase transition under thermal stimulation, and two reversible dielectric-state switches. This compound exhibits strong green photoluminescence under ultraviolet excitation, boasting a quantum yield of 44.36%. Furthermore, it demonstrates a reversible ferroelastic phase transition at 358/348 K. The integration of temperature and photosensitivity in compound 1 opens up new avenues for the development and exploration of a broader spectrum of multifunctional phase transition materials.

引用

页码：21849 / 21855

页数：7

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