Solid-State Reversible Phase Transition and Photoluminescence Properties of Organic-Inorganic Hybrid Halide: (BTPA)2MnBr4

被引：1
|
作者：
Yu, Xincheng [1 ]
Liu, Yao [2 ]
Liu, Yiyuan [1 ]
Li, Shengkai [2 ]
Tan, Haibin [2 ]
Liu, Jinzhen [2 ]
Chen, Zhiguo [1 ]
机构：
[1] Chibi Yuntian New Mat Technol Co Ltd, Xianning 437300, Hubei, Peoples R China
[2] Gannan Univ Sci & Technol, Coll Rare Earth & New Mat Engn, Ganzhou Key Lab Adv Proc & Technol Optimizat High, Ganzhou 341000, Jiangxi, Peoples R China
来源：
INORGANIC CHEMISTRY | 2024年 / 63卷 / 46期
关键词：
DIELECTRIC RESPONSES; PEROVSKITES; PROGRESS;
D O I：
10.1021/acs.inorgchem.4c02359
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Multifunctional materials have long been a popular research area, with organic-inorganic hybrids frequently utilized due to their diverse properties and versatile assembly techniques. In this context, a novel Mn-based organic-inorganic hybrid compound (BTPA)2MnBr4(1) was prepared, with strong green photoluminescence, phase transition under thermal stimulation, and two reversible dielectric-state switches. This compound exhibits strong green photoluminescence under ultraviolet excitation, boasting a quantum yield of 44.36%. Furthermore, it demonstrates a reversible ferroelastic phase transition at 358/348 K. The integration of temperature and photosensitivity in compound 1 opens up new avenues for the development and exploration of a broader spectrum of multifunctional phase transition materials.
引用
收藏
页码：21849 / 21855
页数：7
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