Determination of erbium by using fast neutron induced gamma-ray activation analysis

被引：0

作者：

Cheng, Can ^{[1
,2
]}

Jia, Wenbao ^{[3
]}

Gu, Jiayu ^{[2
]}

Hu, Zunhao ^{[2
]}

Xing, Liteng ^{[2
]}

Xia, Xunrong ^{[2
]}

Zhang, Yan ^{[4
]}

机构：

[1] Nanjing Tech University, Nanjing

[2] Jiangsu Institute of Metrology, Jiangsu Energy Measurement Data Center, Nanjing

[3] Nanjing University of Aeronautics and Astronautics, Nanjing

[4] East China University of Technology, Nanchang

来源：

He Jishu/Nuclear Techniques | 2024年 / 47卷 / 10期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Erbium oxide; Mass detection limit; Neutron generator; Prompt gamma-ray neutron activation analysis;

D O I：

10.11889/j.0253-3219.2024.hjs.47.100202

中图分类号：

学科分类号：

摘要：

]Background] In the process of nuclear fuel generation, neutron poisons are added to enhance performance of nuclear fuel. Erbium is a common neutron poison, and its content needs to be measured and analyzed during the production of such nuclear fuels. The traditional methods have limited penetration and can only analyze the surface of the samples, unable to penetrate the bulk nuclear fuel materials for internal component analysis. Prompt Gamma-ray Neutron Activation Analysis (PGNAA) is a non-destructive testing technique, which is suitable for detecting large samples. ]Purpose] This study aims to explore the feasibility of determining the erbium in large samples based on PGNAA technology. ]Methods] Firstly, a deuterium-tritium (D-T) neutron generator and a high-purity germanium (HPGe) detector were employed to establish a measurement platform. Erbium oxide was selected as the sample, and measurements were conducted utilizing the 815.9 keV peak emitted from the reaction of fast neutrons with erbium. Then, the neutron yield of D-T neutron generator was calculated using copper foil activation and Monte Carlo simulations, and the neutron spectrum at sample position was calculated using Monte Carlo simulation for observing the thermal and fast neutron fluxes. Finally, the calibration curve and mass detection limit were analyzed. ]Results] Measurement results show that the neutron yield of D-T neutron generator is (2.34±0.01)× 106 s-1 and the fast neutron flux at sample position is 106 cm-2∙s-1. Analysis results demonstrate that there is a good linear relationship between the 815.9 keV peak counts and the mass of erbium. The mass detection limit for erbium is 28 g. In addition, there is no interference between the intrinsic gamma ray of238U and the 815.9 keV Er peak. ]Conclusions] This study verifies the feasibility of PGNAA technology for the erbium determination, which can be used for further analysis of erbium in nuclear fuel. © 2024 Science Press. All rights reserved.

引用

共 26 条

[21]

Doron O, Wielopolski L, Mitra S, Et al., MCNP benchmarking of an inelastic neutron scattering system for soil carbon analysis[J], Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 735, pp. 431-436, (2014)

[22]

Szentmiklosi L., Fitting special peak shapes of prompt gamma spectra, Journal of Radioanalytical and Nuclear Chemistry, 315, 3, pp. 663-670, (2018)

[23]

Yakubova G, Kavetskiy A, Prior S A, Et al., Applying Monte-Carlo simulations to optimize an inelastic neutron scattering system for soil carbon analysis[J], Applied Radiation and Isotopes, 128, pp. 237-248, (2017)

[24]

WEI Shuhua, YU Xiaohan, ZOU Yang, Et al., Optimal design of burnable poisons for the advanced plate-type high-temperature reactor, Nuclear Techniques, 38, 1, (2015)

[25]

LI Bisai, Study on TXRF analyzer for rapid detection of uranium element, (2022)

[26]

Wu K, Liu X Y, Yang X, Et al., <sup>235</sup>U enrichment detection system for nuclear fuel rod based on compact D-D neutron generator[J], Science China Technological Sciences, 64, 9, pp. 1940-1946, (2021)

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