Synthesis and spectral tuning of CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+)

被引：0
作者：
Dong, Xiao-Rui [1 ]
Fu, Zuo-Ling [2 ]
Wang, Chang-Geng [3 ]
Zhang, Fang-Cheng [3 ]
机构：
[1] College of Science, Northeast Dianli University, Jilin
[2] College of Physics, Jilin University, Changchun
[3] Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun
来源：
Fu, Zuo-Ling (zlfu@jlu.edu.cn) | 1600年 / Editorial Office of Chinese Optics卷 / 35期
关键词：
CaZrO[!sub]3[!/sub; Optical properties; Rare earth ions; Spectral tuning;
D O I：
10.3788/fgxb20143511.1311
中图分类号：
学科分类号：
摘要：
The orthorhombic CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+) were successfully synthesized by solid-state reaction method. The crystalline structure of the samples were characterized by X-ray diffraction (XRD). The luminescence properties were investigated using photoluminescence spectra. Under appropriate near UV- or blue light-radiation, CaZrO3:Pr3+ showed strong green light emission, CaZrO3:Sm3+ showed well reddish orange light in the range of 550-700 nm, and CaZrO3:Tm3+ generated well blue light emission. The results indicate that spectral tuning can be realized by adjusting active ions in CaZrO3, thus rare earth ions-doped CaZrO3 phosphors can be exploited as new luminescence materials. ©, 2014, Chines Academy of Sciences. All right reserved.
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页码：1311 / 1316
页数：5
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共 30 条
  • [1] Gordon W.O., Carter J.A., Tissue B.M., Long-lifetime luminescence of lanthanide-doped gadolinium oxide naoparticles for immunoassays, J. Lumin., 108, 1-4, pp. 339-342, (2004)
  • [2] Puchalska M., Zych E., The effect of charge compensation by means of Na<sup>+</sup> ions on the luminescece behavior of Sm<sup>3+</sup>-doped CaAl<sub>4</sub>O<sub>7</sub> phosphor, J. Lumin., 132, 3, pp. 826-831, (2012)
  • [3] Zhang S.Y., Nakai Y., Tsuboi T., Et al., Luminescence and microstructural features of Eu-activated LiBaPO<sub>4</sub> phoshor, Chem. Mater., 23, 5, pp. 1216-1224, (2011)
  • [4] Zhang J.H., Lv W., Hao Z.D., Et al., Color-tunable white-light emitting BaMg<sub>2</sub>Al<sub>6</sub>Si<sub>9</sub>O<sub>30</sub>:Eu<sup>2+</sup>, Tb<sup>3+</sup>, Mn<sup>2+</sup> phosphors via energy transfer, Chin. Opt., 5, 3, pp. 203-208, (2012)
  • [5] Iwahara H., Asakura Y., Katahira K., Et al., Prospect of hydrogen technology using proton-donducting ceramic, Solid State Ionics, 168, 3-4, pp. 299-310, (2004)
  • [6] Zhang H., Fu X., Niu S., Et al., Synthesis and photoluminescence properties of Eu<sup>3+</sup>-doped AZrO<sub>3</sub>(A=Ca, Sr, Ba) perovskite, J. Alloys Compd, 459, 1-2, pp. 103-106, (2008)
  • [7] Pan Y., Su Q., Xu H., Et al., Synthesis and red luminescence of Pr<sup>3+</sup>-doped CaTiO<sub>3</sub> nanophosphor from polymer precursor, J. Solid State Chem., 174, 1, pp. 69-73, (2003)
  • [8] Lemanski K., Gagor A., Kurnatowska M., Et al., Spectoscopic properties of Nd<sup>3+</sup> ions in nano-perovskite CaTiO<sub>3</sub>, J. Solid State Chem., 184, 10, pp. 2713-2718, (2011)
  • [9] Zhang J.S., Chen B.J., Liang Z.Q., Et al., Optical transition and thermal quenching mechanism in CaSnO<sub>3</sub>:Eu<sup>3+</sup> phosphors, J. Alloys Compd., 612, 5, pp. 204-205, (2014)
  • [10] He G.G., Liu Y.L., Lei B.F., Luminescence properties of CaSnO<sub>3</sub>:Pr<sup>3+</sup> perovskite phosphor, Chin. J. Lumin., 28, 3, pp. 389-392, (2007)
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