Synthesis and Structure of a Novel Inorganic-organic Hybrid Framework Microporous Material Cd3(BDC)0.5(BTC)2(DMF) (H2O) · 3DMF · H3O · H2O

被引：0

作者：

Shi, Xin ^{[1
]}

Fang, Qian-Rong ^{[1
]}

Xin, Ming-Hong ^{[1
]}

Wu, Gang ^{[1
]}

Tian, Ge ^{[1
]}

Zhu, Guang-Shan ^{[1
]}

Li, Ya-Feng ^{[1
]}

Wang, Li-Feng ^{[1
]}

Wang, Chun-Lei ^{[1
]}

Shang, Tie-Cun ^{[1
]}

Qiu, Shi-Lun ^{[1
]}

机构：

[1] College of Chemistry, State Key Lab. Inorg. Synthesis P., Jilin University, Changchun 130023, China

来源：

Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities | 2002年 / 23卷 / 11期

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摘要：

A new inorganic-organic hybrid framework microporous material Cd3(BDC)0.5(BTC)2· (DMF)(H2O)·3DMF·H3O·H 2O, in which two kinds of carboxylate ligands coordinate with cadmium ions synchronously, was obtained under a mild synthesis condition. The titled compound is crystallized in a monoclinic system, space group P2(1)/c with a=1. 584 7(7) nm, b=1.426 7(6) nm, c=1. 936 3(6) nm, β=113. 186(7)°, V = 4. 024 6(3) nm3, Z = 4, Dx=1. 947 mg/m3, Mr=1 179. 92, μ=1. 662 mm-1, F(000) = 2 344, R = 0. 074 8, wR = 0. 215 1. Three cadmium centers link with each other through BDC or BTC ligand to form a 3-D open framework.

引用

页码：2041 / 2042