Infinite secondary building units and forbidden catenation in metal-organic frameworks

被引：0

作者：

Rosi, Nathaniel L. ^{[1
]}

Eddaoudi, Mohamed ^{[1
]}

Kim, Jaheon ^{[1
]}

O'Keeffe, Michael ^{[2
]}

Yaghi, Omar M. ^{[1
]}

机构：

[1] Materials Design and Discovery Group, Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, United States

[2] Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604, United States

来源：

| 2002年 / Wiley-VCH Verlag卷 / 41期

关键词：

Organometallics;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Interlinked Zn-O-C infinite secondary building units (SBUs) form the basis of the novel metalorganic frameworks (MOFs) [Zn3(OH2)(X)2] &middot 4 DEF &middot 2H2O (MOF-69A: X=4,4′-biphenyldicarboxylate; MOF-69B: X=2,6-naphthalenedicarboxylate; DEF = N,N′-diethylformamide). The nature of the infinite SBUs results in frameworks (structure of MOF-69A depicted) wherein catenation is forbidden.

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