Synthesis of sulfonated poly(arylene ether sulfone)s via direct polymerization

被引：0
|
作者：
Wang, F. [1 ]
Ji, Q. [1 ]
Harrison, W. [1 ]
Mecham, J. [1 ]
Formato, R. [2 ]
Kovar, R. [2 ]
Osenar, P. [2 ]
McGrath, J.E. [1 ]
机构：
[1] Department of Chemistry, NSF Sci. Technol. Ctr. High P., Virginia Polytech. Inst. State Univ., Blacksburg, VA 24061, United States
[2] Foster Miller, 195 Bear Hill Road, Waltham, MA 02154-1196, United States
来源：
| 2000年 / ACS, Washington, DC, United States卷 / 41期
关键词：
Ion exchange membranes - Molecular weight - Monomers - Plastic films - Polymerization - Sulfonation - Synthesis (chemical);
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Poly(arylene ether sulfone)s containing sodium sulfonate groups were prepared by direct polymerization of the sulfonated activated halide using a similar `polysulfone' polymerization conditions. Reaction temperatures were of 190 °C were able to produce high molecular weight in reasonable period of time. Tough film forming membranes with up to 60% of the sulfonated monomer structure were obtained, which would provide good ionic exchange equivalents.
引用
收藏
相关论文
共 50 条
  • [1] Synthesis of sulfonated poly(arylene ether sulfone)s via direct polymerization.
    Wang, F
    Ji, Q
    Harrison, W
    Mecham, J
    McGrath, JE
    Formato, R
    Kovar, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U378 - U378
  • [2] Synthesis of sulfonated poly(arylene ether phosphine oxide sulfone)s via direct polymerization.
    Wang, F
    Mecham, J
    Harrison, W
    Hickner, M
    Kim, Y
    McGrath, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U435 - U435
  • [3] Synthesis of highly sulfonated poly(arylene ether sulfone) random (statistical) copolymers via direct polymerization
    Wang, F
    Hickner, M
    Ji, Q
    Harrison, W
    Mecham, J
    Zawodzinski, TA
    McGrath, JE
    MACROMOLECULAR SYMPOSIA, 2001, 175 : 387 - 395
  • [4] Synthesis of highly sulfonated poly(arylene ether sulfone) random (statistical) copolymers via direct polymerization
    Wang, Feng
    Hickner, Michael
    Ji, Qing
    Harrison, William
    Mecham, Jeffrey
    Zawodzinski, Thomas A.
    McGrath, James E.
    Macromolecular Symposia, 2001, 175 : 387 - 396
  • [5] Synthesis of sulfonated poly(phthalazinone ether sulfone)s by direct polymerization
    Xiao, GY
    Sun, GM
    Yan, DY
    Zhu, PF
    Tao, P
    POLYMER, 2002, 43 (19) : 5335 - 5339
  • [6] Improvement of electrochemical performances of sulfonated poly(arylene ether sulfone) via incorporation of sulfonated poly(arylene ether benzimidazole)
    Hong, Young Taik
    Lee, Chang Hyun
    Park, Hyu. Ng Su
    Min, Kyung A.
    Kim, Hyung Joong
    Nam, Sang Yong
    Lee, Young Moo
    JOURNAL OF POWER SOURCES, 2008, 175 (02) : 724 - 731
  • [7] Synthesis and characterization of controlled molecular weight sulfonated aminofunctional poly(arylene ether sulfone)s prepared by direct polymerization.
    Mecham, JB
    Shobha, HK
    Wang, F
    Harrison, WL
    McGrath, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U313 - U313
  • [8] Adhesion property of sulfonated poly(arylene ether sulfone)s
    Choi, IJ
    Ahn, CJ
    Yoon, TH
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 93 (03) : 1211 - 1218
  • [9] Homogeneous synthesis and characterization of sulfonated poly(arylene ether sulfone)s via chlorosulfonic acid.
    Harrison, W
    O'Connor, K
    Arnett, NY
    McGrath, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U375 - U375
  • [10] Synthesis and properties of sulfonated poly(arylene ether ketone sulfone) copolymer
    Shen, Kunzhi
    Dong, Bo
    Wang, Yan
    Lin, Liming
    Chen, Zheng
    HIGH PERFORMANCE POLYMERS, 2016, 28 (03) : 315 - 321
12345