Charge ordering and lattice modulation in quasi-one-dimensional halogen-bridged binuclear metal complexes

被引：0

作者：

Kuwabara, Makoto ^{[1
]}

Yonemitsu, Kenji ^{[1
]}

机构：

[1] Institute for Molecular Science, Okazaki 444-8585, Japan

来源：

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals | 2000年 / 343卷

关键词：

Electronic structure - Ground state - Halogen elements - Ions - Magnetic properties - Phase diagrams - Raman spectroscopy - Transition metals - Transport properties - X ray diffraction analysis;

D O I：

10.1080/10587250008023501

中图分类号：

学科分类号：

摘要：

Ground state phase diagrams of the MMX chains are studied in a one-dimensional dimerized 3/4-filled model by exactly diagonalizing 12-site clusters. Experimentally observed phases are reproduced by changing relative strengths of an electron-lattice coupling, the inter-dimer transfer integral, and an elastic constant whose variation is roughly estimated from the interatomic spacing, the species of the halogen ions and the presence/absence of counter ions.

引用

页码：47 / 52

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