Iodination of β-keto-sulfones using molecular iodine and hydrogen peroxide in aqueous medium: Facile synthesis of α-iodomethyl sulfones

被引：0

作者：

Suryakiran, Navath ^{[1
]}

Reddy, Thummalapalli Srikanth ^{[1
]}

Venkateswarlu, Yenamandra ^{[1
]}

机构：

[1] Organic Chemistry Division-I, Natural Products Laboratory, Indian Institute of Chemical Technology

来源：

Journal of Sulfur Chemistry | 2007年 / 28卷 / 05期

关键词：

Iodination; α-Iodomethyl sulfones; β-Keto-sulfones;

D O I：

10.1080/17415990701595865

中图分类号：

学科分类号：

摘要：

The reaction of β-keto-sulfones with molecular iodine in the presence of aqueous acidic hydrogen peroxide yielded α-iodo β-keto-sulfones, which on treatment with aqueous alkali at room temperature underwent base-induced cleavage to afford corresponding α-iodomethyl sulfones in excellent yields. © 2007 Taylor & Francis.

引用

页码：471 / 476

页数：5

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