A study of the optical bandgap energy and Urbach tail of spray-deposited CdS:In thin films

被引:0
作者
机构
[1] Faculty of Information Technology, Department of Basic Sciences-Physics, Al Isra University, Amman
[2] Faculty of Science, Physics Department, University of Jordan, Amman
关键词
Cadmium sulfide; Optical bandgap; Solar cells; Thin films; Urbach tail;
D O I
10.1016/j.jmrt.2013.02.012
中图分类号
学科分类号
摘要
Cadmium sulfide (CdS) is an interesting material for applications in optoelectronic and photovoltaic devices. In particular, thin films of n-type CdS are widely used as a window layer in heterojunction solar cells. The optical bandgap energy is the most interesting parameter for these applications. For spray-deposited indium-doped cadmium sulfide (CdS:In) thin films prepared on glass substrates the transmittance measurements were used to estimate the optical bandgap energy. Tailing in the bandgap was observed and found to obey Urbach rule. The effects of film thickness and the substrate temperature on the bandgap energy and the width of the tail were investigated. A linear relation between bandgap energy and width of the tail was found. © 2013 Brazilian Metallurgical, Materials and Mining Association.
引用
收藏
页码:221 / 227
页数:6
相关论文
共 25 条
[1]  
Perna G., Capozzi V., Ambrico M., Augelli V., Ligonzo T., Minafra A., Structural and optical characterization of undoped CdS films grown by pulsed laser deposition, Thin Solid Films, 453-454, pp. 187-194, (2004)
[2]  
Patidar D., Sharma R., Jain N., Sharma T.P., Saxena N.S., Optical properties of CdS sintered film, Bull Mater Sci, 29, pp. 21-24, (2006)
[3]  
Tsai C.T., Chuu D.S., Chen G.L., Yang S.L., Studies of grain size effects in rf sputtered CdS thin films, J Appl Phys, 79, pp. 9105-9109, (1996)
[4]  
Metin H., Esen R., Photoconductivity studies on CdS films grown by chemical bath deposition technique, Erciyes Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 19, pp. 96-102, (2003)
[5]  
Ariza-Calderon H., Lozada-Morales R., Zelaya-Angel O., Mendoza-Alvarez G.J., Banos L., Photoluminescence measurements in the phase transition region for CdS thin films, J Vac Sci Technol A, 14, pp. 2480-2482, (1996)
[6]  
De Melo O., Hernandez L., Zelaya-Angel O., Lozada-Morales R., Becerril M., Vasco E., Low resistivity cubic phase CdS films by chemical bath deposition technique, Appl Phys Lett, 65, pp. 1278-1280, (1994)
[7]  
Vigil O., Riech I., Garcia-Rocha M., Zelaya-Angle O., Characterization of defect levels in chemically deposited CdS films in the cubic-to hexagonal phase transition, J Vac Sci Technol A, 15, pp. 2282-2286, (1997)
[8]  
Ikhmayies S.J., Production and Characterization of CdS/CdTe Thin Film Photovoltaic Solar Cells of Potential Industrial Use. Ph.D. Dissertation, (2002)
[9]  
Ikhmayies S.J., Ahmad-Bitar R.N., The influence of the substrate temperature on the photovoltaic properties of spray-deposited CdS:In thin films, Appl Surf Sci, 256, pp. 3541-3545, (2010)
[10]  
Ikhmayies S.J., Ahmad-Bitar R.N., Effects of processing on the electrical and structural properties of spray-deposited CdS:In thin films, Phys B Condens Matter, 404, pp. 2419-2424, (2009)