Unravelling the electrochemistry of Ni-MOF derived nickel phosphide/carbon composite electrode and redox additive electrolyte for high performance supercapacitors

被引：3

作者：

Dubey P. ^{[1
]}

Mansi ^{[2
]}

Holdynski M. ^{[3
]}

Deep A. ^{[4
]}

Tiwari U.K. ^{[2
]}

Nogala W. ^{[3
]}

Shrivastav V. ^{[3
]}

Sundriyal S. ^{[5
]}

机构：

[1] Advanced Carbon Products and Metrology Department, CSIR-National Physical Laboratory (CSIR-NPL), New Delhi

[2] CSIR-Central Scientific Instruments Organisation, Sector 30-C, Chandigarh

[3] Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, Warsaw

[4] Institute of Nano Science and Technology (INST), Sector-81, Punjab, Mohali

[5] Regional Center of Advanced Technologies and Materials, The Czech Advanced Technology and Research Institute (CATRIN), Palacký University Olomouc, Šlechtitelů 27, Olomouc

来源：

Materials Today Chemistry | 2024年 / 39卷

基金：

欧盟地平线“2020”;

关键词：

Energy density; Ni MOF; Phosphide; Redox electrolyte; Supercapacitor;

D O I：

10.1016/j.mtchem.2024.102165

中图分类号：

学科分类号：

摘要：

The performance and operation of an energy storage device are significantly influenced by the electrolyte and electrode materials. Therefore, it is crucial to develop an electrode material with a rational design and achieve compatibility with the electrolyte. In this study, we prepare Ni-MOF derived nickel phosphides/carbon (NP@C) nanostructure as an electrode for supercapacitor application. The as synthesized material provides more redox-active sites, better spatial utilization, improved conductivity, and a high-polarized surface that will speed up ion migration at electrode/electrolyte. Also, the usage of redox additive electrolyte (0.2 M K3[Fe (CN)6] in 1 M Na2SO4) further complements the redox active sites and hence the improved charge transport. Therefore, NP@C electrode achieved a remarkable 2136.3 F/g of capacitance at 3 A/g with 90.6 % of capacitance retention after 5000 charge-discharge cycles. In addition, the surface-diffusion studies confirms that NP@C shows high diffusion contribution of 82.6 % in redox electrolyte than that of 25.1 % in 1 M Na2SO4. Furthermore, NP@C//NP@C symmetric supercapacitor device in redox additive electrolyte also delivered remarkable performance rendering high energy density of 52.5 Wh/kg at a power density of 750 W/kg. In addition, NP@C//NP@C also shows the long-term stability with attenuating only 7.2 % of initial capacitance value after 10000 charge-discharge cycles. In addition to this, the device performs extremely well when tested for self-discharge studies. Hence, this study demonstrates the perfect harmony of NP@C electrodes and redox additive electrolyte to fabricate a high-performance supercapacitor. © 2024

引用

共 57 条

[51]

Bairwa B., Pareek K., Sarvagya M., Yaragatti U.R., Analysis of leakage current mechanism in supercapacitor with experimental approach, 2022 IEEE Fourth International Conference on Advances in Electronics, Computers and Communications (ICAECC), pp. 1-6, (2022)

[52]

Kaur A., Shrivastav V., Dubey P., Deep A., Mudahar I., Sundriyal S., Mishra S., Waste paper-derived porous carbon incorporated with mesoporous ZIF-8 crystals for symmetrical supercapacitors, Energy Fuels, 37, 15, pp. 11376-11387, (2023)

[53]

Xiong G., He P., Lyu Z., Chen T., Huang B., Chen L., Fisher T.S., Bioinspired leaves-on-branchlet hybrid carbon nanostructure for supercapacitors, Nat. Commun., 9, 1, (2018)

[54]

Lv Z., Zhong Q., Bu Y., In-situ conversion of rGO/Ni2P composite from GO/Ni-MOF precursor with enhanced electrochemical property, Appl. Surf. Sci., 439, pp. 413-419, (2018)

[55]

Hu Y.-M., Liu M.-C., Hu Y.-X., Yang Q.-Q., Kong L.-B., Han W., Li J.-J., Kang L., Design and synthesis of Ni2P/Co3V2O8 nanocomposite with enhanced electrochemical capacitive properties, Electrochim. Acta, 190, pp. 1041-1049, (2016)

[56]

Banerjee P.C., Lobo D.E., Middag R., Ng W.K., Shaibani M.E., Majumder M., Electrochemical capacitance of Ni-doped metal organic framework and reduced graphene oxide composites: more than the sum of its parts, ACS Appl. Mater. Interfaces, 7, 6, pp. 3655-3664, (2015)

[57]

Jayakumar A., Antony R.P., Wang R., Lee J.-M., MOF-derived hollow cage NixCo3−xO4 and their synergy with graphene for outstanding supercapacitors, Small, 13, 11, (2017)

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