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Enhancement in dielectric, ferroelectric, and piezoelectric properties of BaTiO3- modified Bi0.5(Na0.4K0.1)TiO3 lead-free ceramics
被引:0
作者
:
Vuong, Le Dai
论文数:
0
引用数:
0
h-index:
0
机构:
Hue Industrial College, Viet Nam
Hue Industrial College, Viet Nam
Vuong, Le Dai
[
1
]
Gio, Phan Dinh
论文数:
0
引用数:
0
h-index:
0
机构:
University of Sciences, Hue University, Viet Nam
Hue Industrial College, Viet Nam
Gio, Phan Dinh
[
2
]
机构
:
[1]
Hue Industrial College, Viet Nam
[2]
University of Sciences, Hue University, Viet Nam
来源
:
Journal of Alloys and Compounds
|
2021年
/ 817卷
关键词
:
In this paper;
the effect of BaTiO3 on dielectric;
ferroelectric;
and piezoelectric properties was observed in (1-x)[Bi0.5(Na0.4K0.1)TiO3] – xBaTiO3 ceramics (BNKT-BT;
with x = 0;
0.01;
0.02;
0.03 and 0.04). The phase formation and microstructure of BNKT-BT ceramics were examined by X-ray diffraction (XRD);
the Raman scattering spectra;
and scanning electron microscopy (SEM). A pure perovskite phase was observed in the ceramic samples;
proving the dissolution of BaTiO3 into the lattice structure of the BNKT to form a homogeneous solid solution (x ≤ 0.04). At x = 0.02;
the best physical properties of the BNKT-BT ceramics;
such as density;
ρ = 5.86 g/cm3 (98.5% of the theoretical density);
electromechanical coupling factors (kp);
0.30;
(kt);
0.31;
remanent polarization (Pr);
17.2 μC cm−2;
dielectric constant (Εr);
1354;
and highest dielectric constant (Εmax);
4037;
were obtained. Further;
the energy storage properties of 0.98Bi0.5(Na0.4K0.1)TiO3 – 0.02BaTiO3 ceramics were studied and compared with the textured ceramics (the same composition);
which were formed due to the high degree of orientation obtained by the template grain growth method. The textured ceramics showed lower remnant polarization;
while the piezoelectric coefficient (d31) and electromechanical coupling coefficients (kp and kt) of the textured ceramics were found to increase by about 8%;
13.3%;
and;
19.4%;
respectively. © 2019 Elsevier B.V;
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