Improving enzymatic hydrolysis effect of herb residue by deep eutectic solvent pretreatment

被引:0
|
作者
Xie X. [1 ]
Liu Y. [1 ]
Yu Q. [2 ]
Zhang Y. [2 ]
Zhang R. [1 ]
Qiu Y. [1 ]
机构
[1] College of Mechanical and Electrical Engineering, Shaanxi University of Science & Technology, Xi'an
[2] Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou
关键词
Deep eutectic solvent; Enzymatic hydrolysis; Fractal-like kinetics; Herb residue; Pretreatment;
D O I
10.16085/j.issn.1000-6613.2021-1764
中图分类号
学科分类号
摘要
In recent years, deep eutectic solvent (DES) has attracted extensive attention in biomass pretreatment owing to its advantages of easy preparation, low cost and easy recovery. In this study, DES was synthesized with choline chloride as hydrogen bond receptor and ethanolamine as hydrogen bond donor. The effects of pretreatment conditions of different temperature, time and solid-liquid ratio on the components and enzymatic hydrolysis of herb residue were studied. The results showed that, the lignin removal rate was 78.42% and the cellulose recovery rate was 83.89% after pretreatment at 120℃ for 4 hours with the solid-liquid ratio of 1:20. After 96 hours of enzymatic hydrolysis, it was found that the enzymatic hydrolysis efficiency of the substrate under the optimal conditions was 78.57%, which was 1.58 times higher than that of untreated herb residue(30.40%). Fractal like kinetic analysis showed that the pretreatment temperature had the greatest impact on the enzymatic hydrolysis effect. SEM, XRD and FTIR analysis showed that the changes of substrate morphology, crystallization index and functional group after pretreatment were conducive to the improvement of enzymatic hydrolysis effect. © 2022, Chemical Industry Press Co., Ltd. All right reserved.
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页码:1349 / 1356
页数:7
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共 20 条
  • [1] YAN X, CHENG J R, WANG Y T, Et al., Enhanced lignin removal and enzymolysis efficiency of grass waste by hydrogen peroxide synergized dilute alkali pretreatment, Bioresource Technology, 301, (2020)
  • [2] HALDAR D, PURKAIT M K., A review on the environment-friendly emerging techniques for pretreatment of lignocellulosic biomass: Mechanistic insight and advancements, Chemosphere, 264, (2021)
  • [3] DING N, LIU H, SUN Y, Et al., Lignin degradation in cooking with active oxygen and solid Alkali process: a mechanism study, Journal of Cleaner Production, 278, (2021)
  • [4] DONG Yanmei, HONG Yuanfang, MA Yangyang, Et al., Ethanolamine-based deep eutectic solvent pretreatment of wheat straw to improve its polysaccharide enzymatic hydrolysis efficiency, Modern Food Science and Technology, 37, 7, pp. 46-56, (2021)
  • [5] XIE Yitong, GUO Xin, Yanna LYU, Et al., Research progress on the dissolution of lignocellulose and separation of its components by deep eutectic solvents, Chemistry and Industry of Forest Products, 39, 5, pp. 11-18, (2019)
  • [6] ZHANG Heng, WANG Zhe, GAO Hongkun, Et al., Research progress of cellulose catalytic conversion for preparation of 5-HMF in different solvents, Transactions of China Pulp and Paper, 33, 4, pp. 70-76, (2018)
  • [7] SATLEWAL A, AGRAWAL R, BHAGIA S, Et al., Natural deep eutectic solvents for lignocellulosic biomass pretreatment: recent developments, challenges and novel opportunities, Biotechnology Advances, 36, 8, pp. 2032-2050, (2018)
  • [8] LI A L, HOU X D, LIN K P, Et al., Rice straw pretreatment using deep eutectic solvents with different constituents molar ratios: biomass fractionation, polysaccharides enzymatic digestion and solvent reuse, Journal of Bioscience and Bioengineering, 126, 3, pp. 346-354, (2018)
  • [9] ZHANG C W, XIA S Q, MA P S., Facile pretreatment of lignocellulosic biomass using deep eutectic solvents, Bioresource Technology, 219, pp. 1-5, (2016)
  • [10] AYYACHAMY M, GUPTA V K, CLIFFE F E, Et al., Enzymatic Saccharification of lignocellulosic biomass, (2013)