Modification of Epoxy Resin Composites with Thermo-Oxidative Aging Properties

被引:0
作者
Liu H. [1 ]
Fan D. [2 ]
Li Y. [1 ]
Zhang Y. [3 ]
Liang Z. [3 ]
Hu B. [3 ]
He M. [3 ]
Xie Z. [3 ]
Zhang X. [2 ]
机构
[1] Dongfang Electric Company Academy of Science and Technology Co., Ltd., Chengdu
[2] State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu
[3] Dongfang Electric Machinery Company Limited, Deyang
来源
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2021年 / 37卷 / 08期
关键词
Epoxy resin; Graphene; Resistance to thermo-oxidative aging;
D O I
10.16865/j.cnki.1000-7555.2021.0204
中图分类号
学科分类号
摘要
In view of the disadvantages of epoxy resin composite materials such as poor thermal oxygen aging performance and white surface, carbon nanotubes, graphene and molybdenum dioxide were used as modified filler to study the effects of three fillers and their composite epoxy resin composite on thermal oxygen aging performance. The results of resistance test show that the addition of fillers could delay the rising trend of resistance of epoxy resins in the process of thermal oxygen aging to some extent, among which the effect of graphene is the most obvious. At the same time, the macroscopic aging performance of the samples and the SEM microscopic images show that the introduction of graphene and other lamellar nano-fillers has a positive effect on aging retardation, and can significantly improve the surface whitening of epoxy resin composites during aging process. © 2021, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
引用
收藏
页码:102 / 109
页数:7
相关论文
共 12 条
  • [1] Xie R B, Xue J, Chen S, Et al., Research on damp and heat aging characteristics of epoxy resin, Insulating Materials, 52, 6, pp. 21-29, (2019)
  • [2] Malamud R, Cheremisov I., Anti-corona protection of the high voltage stator windings and semi-conductive materials for its realization, Conference Record of the 2000 IEEE International Symposium on Electrical Insulation (Cat. No. 00CH37075), pp. 32-35, (2000)
  • [3] Zhang D J, Liu G, Bao J W, Et al., Environmental aging performance and mechanism of T700 carbon fiber reinforced epoxy resin matrix composites, Acta Materiae Compositae Sinica, 33, 7, pp. 1390-1399, (2016)
  • [4] Luoma G A, Rowland R D., Environmental degradation of an epoxy resin matrix, Journal of Applied Polymer Science, 32, pp. 5777-5790, (1986)
  • [5] Parvizi A, Garrett K W, Bailey J E., Constrained cracking in glass fiber-reinforced epoxy cross-ply laminates, Journal of Materials Science, 13, pp. 195-201, (1978)
  • [6] Liu S X, Yang J L, Huang Y J, Et al., Review on the effect of graphene on the flame retardancy and aging properties of polymeric materials, Materials China, 35, 11, pp. 843-848, (2016)
  • [7] Zhou K, Jiang S, Bao C, Et al., Preparation of poly (vinyl alcohol) nanocomposites with molybdenum disulfide (MoS<sub>2</sub>): structural characteristics and markedly enhanced properties, RSC Advances, 2, pp. 11695-11703, (2012)
  • [8] Liu S, Yan H, Fang Z, Et al., Effect of graphene nanosheets and layered double hydroxides on the flame retardancy and thermal degradation of epoxy resin, RSC Advances, 4, pp. 18652-18659, (2014)
  • [9] Ahamad T, Alshehri S M., Thermal degradation and evolved gas analysis of epoxy (DGEBA)/novolac resin blends (ENB) during pyrolysis and combustion, Journal of Thermal Analysis and Calorimetry, 111, pp. 445-451, (2013)
  • [10] Xie W, Yang Z, Cheng X, Et al., Study on thermo-oxygen aging characteristics of epoxy resin material, Transactions of China Electrotechnical Society, 35, 20, pp. 4397-4404, (2020)