The effect of protonation on structural modification in layers

被引：0
作者：
Borodin Y. [1 ]
Zadorozhnaya T. [1 ]
Ghyngazov S. [1 ]
机构：
[1] Tomsk Polytechnic University, 30 Lenin Avenue, Tomsk
来源：
Materials Science Forum | 2019年 / 942卷
关键词：
Protonation; Structural modification; Superlattice;
D O I：
10.4028/www.scientific.net/MSF.942.21
中图分类号：
学科分类号：
摘要：
The results on protonation in solutions and melts of salts and acids, as well as structural changes associated with the formation of nanocomposition structure of materials are discussed. It is demonstrated by structural methods that proton localization is invariant to the volume in the protonated layer and is accompanied by changes between oxygen distances, enlargement of the unit cell and transition to the rhombic phase. Having the maximum crystal-chemical activity, protons create the hexagonal lattice in accordance with the features of equipotential pictures of their nonequilibrium electrostatic fields. The increase in the integral intensity of reflexes observed on neutronograms of protonated LiNbO3 (102), (111), (113) is associated with the ordering of protons in the hexagonal oxygen sublattice of the initial phase. © 2019 Trans Tech Publications, Switzerland.
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页码：21 / 29
页数：8
相关论文
共 39 条
[1]  
Rudnev S.V., Application of elliptic Riemannian geometry to problems of crystallography, Comput. Math. Applic., 6, 5-8, pp. 597-616, (1988)
[2]  
P Johnson N.M., Ponce F.A., Street R.A., Nemanich R.J., Defects in single-crystal silicon induced by hydrogenation, Phys Rev, B35, 8, (1987)
[3]  
Sutulin S.N., Vereshchagin V.I., Rudnev S.V., IR spectroscopy studies of OH-groups in H:LiNbO<sub>3</sub>, News AS USSR, Ser. Inorganic Material, 25, 10, pp. 1923-1925, (1990)
[4]  
Furukawa S., Miyasato T., Three-dimensional quantum well effects in ultrafiae silicon particles, Jap. J. Appl. Phys, 27, 11, pp. L2207-L2209, (1988)
[5]  
Berezin A.A., Isotopic superlattices and isotopicaliy ordered structures, Solid State Соmmun., 54, 8, pp. 819-82I, (1988)
[6]  
Borodin Y.V., Ermolaev D.S., Pak V., Zhang K., Research of nanocomposite structure of boron nitride at proton radiation, IOP Conference Series: Materials Science and Engineering, 110, 1, (2016)
[7]  
Fourguet I.L., Rcriou M.F., de Papeet R., La reaction d'ecn-ange topotactique LiNbO<sub>3</sub>-HNbO<sub>3</sub> on milieu scide, Revue De Chimie Minerale, 21, 2, pp. 385-590, (1984)
[8]  
Fourguuet I.L., Et al., HHbO<sub>3</sub>: Structure and NMR study, Solid State Ionika, North-Holland Publishing Company, 9, 10, pp. 1011-1044, (1983)
[9]  
Yan Y., Fang D., Lin Peng J., Nursill L.A., Electron micioscopic and diffraction study of proton-exchanged LiNbO<sub>3</sub>, Ferroelectrics, 77, 1, pp. 91-100, (1988)
[10]  
Borodin Y.V., Sergeev A.N., The formation of nanocomposition structure in crystals,2008 Proceedings of the 3rd International Forum on Strategic Technology, IFOST, 2008, pp. 174-176, (2008)
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