Research Progresses of Photoluminescence and Application for Emerging Zero-dimensional Metal Halides Luminescence Materials

被引:0
作者
Su B.-B. [1 ]
Xia Z.-G. [1 ,2 ]
机构
[1] The State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Engineering, South China University of Technology, Guangzhou
[2] School of Physics and Optoelectronics, South China University of Technology, Guangzhou
来源
Faguang Xuebao/Chinese Journal of Luminescence | 2021年 / 42卷 / 06期
基金
中国国家自然科学基金;
关键词
LED application; Metal halides; Photoluminescence;
D O I
10.37188/CJL.20210088
中图分类号
学科分类号
摘要
Zero-dimensional(0D) metal halides belong to a new kind of luminescent materials, and they have the unique "host-guest" structure, in which the isolated anionic metal halide polyhedrons are regularly distributed in the main body of organic cations or alkali metal ions. Generally, 0D metal halides with relatively "soft" lattice usually present broad band emission with large Stokes shift, and their luminescence mechanism is mainly derived from self-trapped excitons(STEs) recombination. By screening different metal halide polyhedrons with diversified configurations, one can combine them with appropriate organic cations or alkali metal ions to form new 0D metal halides with different structure types. The obtained 0D metal halides show rich STEs luminescence properties, and their tunable fluorescence emission can be available to cover the entire visible light region. Moreover, it can also realize single-phase white light emission or near infrared emission, making them become a hot spot in the field of photoluminescence materials. Based on our work and others in this field, the photoluminescence mechanisms of 0D metal halides are firstly discussed in this review. Secondly, the luminescence properties and applications of 0D metal halide materials with different polyhedron configurations are introduced. Finally, the key scientific problems of 0D metal halides during the development are summarized, and the future research direction is briefly proposed. © 2021, Science Press. All right reserved.
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页码:733 / 754
页数:21
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共 102 条
  • [1] LI M Z, XIA Z G., Recent progress of zero-dimensional luminescent metal halides, Chem. Soc. Rev, 50, 4, pp. 2626-2662, (2021)
  • [2] AKKERMAN Q A, ABDELHADY A L, MANNA L., Zero-dimensional cesium lead halides: history, properties, and challenges, J. Phys. Chem. Lett, 9, 9, pp. 2326-2337, (2018)
  • [3] ZHOU C K, XU L J, LEE S J, Et al., Recent advances in luminescent zero-dimensional organic metal halide hybrids, Adv. Opt. Mater, (2020)
  • [4] TAN Z F, CHU Y M, CHEN J X, Et al., Lead-free perovskite variant solid solutions Cs<sub>2</sub>Sn<sub>1-x</sub>Te<sub>x</sub>Cl<sub>6</sub>: bright luminescence and high anti-water stability, Adv. Mater, 32, 32, (2020)
  • [5] CHANG T, WEI Q L, ZENG R S, Et al., Efficient energy transfer in Te<sup>4+</sup>-doped Cs<sub>2</sub>ZrCl<sub>6</sub> vacancy-ordered perovskites and ultrahigh moisture stability via A-site Rb-alloying strategy, J. Phys. Chem. Lett, 12, 7, pp. 1829-1837, (2021)
  • [6] ZHU D X, ZAFFALON M L, PINCHETTI V, Et al., Bright blue emitting Cu-doped Cs<sub>2</sub>ZnCl<sub>4</sub> colloidal nanocrystals, Chem. Mater, 32, 13, pp. 5897-5903, (2020)
  • [7] SU B B, MOLOKEEV M S, XIA Z G., Mn<sup>2+</sup>-based narrow-band green-emitting Cs<sub>3</sub>MnBr<sub>5</sub> phosphor and the performance optimization by Zn<sup>2+</sup> alloying, J. Mater. Chem. C, 7, 36, pp. 11220-11226, (2019)
  • [8] TAN Z F, LI J H, ZHANG C, Et al., Highly efficient blue-emitting Bi-doped Cs<sub>2</sub>SnCl<sub>6</sub> perovskite variant: photoluminescence induced by impurity doping, Adv. Funct. Mater, 28, 29, (2018)
  • [9] LI Z Y, LI Y, LIANG P, Et al., Dual-band luminescent lead-free antimony chloride halides with near-unity photoluminescence quantum efficiency, Chem. Mater, 31, 22, pp. 9363-9371, (2019)
  • [10] ZHANG H H, LIAO Q, WU Y S, Et al., Pure zero-dimensional Cs<sub>4</sub>PbBr<sub>6</sub> single crystal rhombohedral microdisks with high luminescence and stability, Phys. Chem. Chem. Phys, 19, 43, pp. 29092-29098, (2017)