Viscoelasticity and dynamical gaps: Rigidity in crystallization and glass-forming liquids

被引：4
作者：
Toledo-Marín J.Q. [1 ]
Naumis G.G. [1 ]
机构：
[1] Departamento de Sistemas Complejos, Instituto de Física, Universidad Nacional Autónoma de México (UNAM), Apartado Postal 20-364, México, 01000, Distrito Federal
来源：
Journal of Non-Crystalline Solids: X | 2019年 / 3卷
关键词：
Relaxation; Rigidity; Viscoelasticity;
D O I：
10.1016/j.nocx.2019.100030
中图分类号：
学科分类号：
摘要：
Rigidity plays an important role on the relaxation properties of glass forming melts, yet it is usually determined from the average coordination number through the chemical composition. A discussion is presented on how viscoelasticity can be used as an alternative way to determine glass rigidity and to give clues about the relaxation processes. It is shown that the transverse current dynamical structure factor of dense glass and crystal forming fluids contain rich information about rigidity that can be related with the presence of a dynamical-gap for transversal vibrational-modes. Then, the number of floppy modes can be related with the dynamical gap size and with the liquid relaxation time. Furthermore, a dynamical average effective coordination number can be defined. Numerical simulations for hard-disks in a dense fluid phase are provided. A discussion is presented on the need to improve glass viscoelasticity models to describe consistently non-exponential stress and strain relaxation. © 2019
引用
收藏
相关论文
共 79 条
  • [71] Abyzov A.S., Fokin V.M., Rodrigues A.M., Zanotto E.D., Schmelzer J.W., The effect of elastic stresses on the thermodynamic barrier for crystal nucleation, J. Non-Cryst. Solids, 432, pp. 325-333, (2016)
  • [72] Grassia L., D'Amore A., Constitutive law describing the phenomenology of subyield mechanically stimulated glasses, Phys. Rev. E, 74, 2, (2006)
  • [73] Grassia L., D'Amore A., On the interplay between viscoelasticity and structural relaxation in glassy amorphous polymers, J. Polym. Sci. B Polym. Phys., 47, 7, pp. 724-739, (2009)
  • [74] Grassia L., D'Amore A., The relative placement of linear viscoelastic functions in amorphous glassy polymers, J. Rheol., 53, 2, pp. 339-356, (2009)
  • [75] Grassia L., D'Amore A., Isobaric and isothermal glass transition of pmma: pressure-volume-temperature experiments and modelling predictions, J. Non-Cryst. Solids, 357, 2, pp. 414-418, (2011)
  • [76] Grassia L., Carbone M.G.P., Mensitieri G., D'Amore A., Modeling of density evolution of pla under ultra-high pressure/temperature histories, Polymer, 52, 18, pp. 4011-4020, (2011)
  • [77] Ramos A., Hutchinson J., Kovacs A., Isobaric thermal behavior of glasses during uniform cooling and heating. Iii. Predictions from the multiparameter kahr model, J. Polym. Sci. Polym. Phys. Ed., 22, 9, pp. 1655-1696, (1984)
  • [78] McKenna G.B., Physical aging in glasses and composites, Long-Term Durability of Polymeric Matrix Composites, pp. 237-309, (2012)
  • [79] Grassia L., Carbone M.G.P., D'Amore A., Modeling of the isobaric and isothermal glass transitions of polystyrene, J. Appl. Polym. Sci., 122, 6, pp. 3751-3756, (2011)
12345678