Mechanical and Dielectric Properties of Elastomer/Polypropylene and Plastomer/Polypropylene Composites

被引:0
|
作者
Zhao H. [1 ]
Yuan X. [1 ]
Yang J. [1 ]
Zhao X. [1 ]
Shi Q. [1 ]
He L. [1 ]
Yang X. [1 ]
机构
[1] Key Lab of Engineering Dielectrics and Their Application, Ministry of Education, Harbin University of Science and Technology, Harbin
关键词
Dielectric properties; Elastomer; Mechanical properties; Plastomer; Polypropylene;
D O I
10.16865/j.cnki.1000-7555.2020.0231
中图分类号
学科分类号
摘要
PP was used as matrix resin, polyolefin elastomer(POE) and polyolefin plastomer(POP) were used as filler to prepare POE/PP and POP/PP with different components. The results of the mechanical properties of the blending system show that POP is weaker than POE at the same content for reducing elastic modulus of PP and effects of toughening modification, however when the POP content is increased to 40%, its mechanical properties are similar to those with the POE content of 30%; the electrical conductivity and alternating current/direct current (AC/DC) breakdown strength show that POP can highly maintain the electrical properties of PP; by observing the microscopic morphologies of the blends, it is found that the dispersion of POE in PP is poor, and POP at less monomer content shows less damage to the crystal regularity of PP, and the similar molecular structure of POP shows better compatibility with PP, which is the reason for the superior electrical properties, representing potential engineering application value. © 2020, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
引用
收藏
页码:44 / 50
页数:6
相关论文
共 12 条
  • [1] Montanari G C, Seri P, Lei X, Et al., Next generation polymeric high voltage direct current cables-A quantum leap needed, IEEE Electrical Insulation Magazine, 34, pp. 24-31, (2018)
  • [2] He J L, Peng L, Zhou Z., Environmental protection of high voltage dc cable insulation materials, High Voltage Technology, 43, 2, pp. 7-13, (2017)
  • [3] Du B X, Hou Z H, Xu H, Et al., Research achievements in polypropylene and polypropylene/inorganic nanocomposites for HVDC cable insulation, High Voltage Technology, 43, 9, pp. 7-18, (2017)
  • [4] Lau K Y, Piah M., Polymer nanocomposites in high voltage electrical insulation perspective: a review, Malaysian Polymer Journal, 6, pp. 58-69, (2011)
  • [5] Tao G L, Liao X J, Fang J B, Et al., Different elastomer on the synergistic toughening polypropylene, Polymer Materials Science & Engineering, 29, 3, pp. 55-59, (2013)
  • [6] Zhou Y, He J, Hu J, Et al., Evaluation of polypropylene/polyolefin elastomer blends for potential recyclable HVDC cable insulation applications, IEEE Transactions on Dielectrics and Electrical Insulation, 22, pp. 673-681, (2015)
  • [7] Liu X., LG POE product overview and applications, New Chemical Materials, 40, 4, pp. 156-157, (2012)
  • [8] Yang J, Zhang Y, Zhang Y., Brittle-ductile transition of PP/POE blends in both impact and high speed tensile tests, Polymer, 44, pp. 5047-5052, (2003)
  • [9] Gupta A K, Purwar S N., Dynamic mechanical and impact properties of PP/SEBS blend, Journal of Applied Polymer Science, 31, pp. 535-551, (2010)
  • [10] Das V, Gautam S S, Pandey A K., Effect of SBS content on low temperature impact strength, morphology and rheology of PP-cp/SBS blends, Polymer-Plastics Technology and Engineering, 50, pp. 825-832, (2011)