Characterization of g-C3N4/Fe2O3 Composite Catalyst and Its Catalytic Effect on Ammonium Perchlorate

被引:0
作者
Wang R.-H. [1 ]
Song W.-K. [1 ]
Guo C.-P. [1 ]
Ji W. [1 ]
Wang D.-J. [1 ]
机构
[1] Sichuan Co-Innovation Center for New Energetic Materials, Southwest University of Science and Technology, Mianyang
来源
Tuijin Jishu/Journal of Propulsion Technology | 2022年 / 43卷 / 05期
关键词
Ammonium perchlorate; Catalyst; Fe[!sub]2[!/sub]O[!sub]3[!/sub; G-C[!sub]3[!/sub]N[!sub]4[!/sub; Solid propellant;
D O I
10.13675/j.cnki.tjjs.210103
中图分类号
学科分类号
摘要
In order to improve the thermal decomposition performance of AP in solid propellant and reduce its thermal decomposition temperature, the morphology and structure of g-C3N4/Fe2O3 obtained in situ were characterized by SEM, XRD and FT-IR, and the catalytic effect of AP thermal decomposition was investigated by Differential Scanning Calorimeter(DSC). The results show that the composite structure of g-C3N4/Fe2O3 was complete, and the Fe2O3 particles were closely loaded on g-C3N4.When different mass fraction of composite catalyst was added, the low temperature decomposition peak and high temperature decomposition peak of AP were significantly reduced, and the catalytic effect was enhanced with the increase of catalyst addition amount. When the mass fraction of composite catalyst was 5%, the high temperature decomposition peak and the low temperature decomposition peak of AP reduced respectively to 348.1℃ and 281.7℃. These results indicate that g-C3N4/Fe2O3 composite catalyst could effectively reduce the thermal decomposition temperature of AP and improve its thermal decomposition performance. © 2022, Editorial Department of Journal of Propulsion Technology. All right reserved.
引用
收藏
页码:368 / 373
页数:5
相关论文
共 22 条
  • [1] Zhong H, Cheng Z P, Zhang L, Et al., Synthesis of Flower-Like and Dendritic Platinum Nanostructures with Excellent Catalytic Activities on Thermal Decomposition of Ammonium Perchlorate, Materials Research Bulletin, 77, pp. 54-59, (2016)
  • [2] Igor L D, Kyrill Y S, Tatyana K S, Et al., Bipyrazole Bearing Ten Nitro Groups-Novel Highly Dense Oxidizer for Forward-Looking Rocket Propulsions, Journal of Materials Chemistry A, 6, 30, pp. 14780-14786, (2018)
  • [3] CAO Chen, XIE Li-feng, LI Bin, Preparation and Characterization of AP/RDX Co-Crystal Coated Micron Aluminum Powder, Journal of Propulsion Technology, 41, 12, pp. 2868-2873, (2020)
  • [4] Vargeese A A., A Kinetic Investigation on the Mechanism and Activity of Copper Oxide Nanorods on the Thermal Decomposition of Propellants, Combustion and Flame, 165, 3, pp. 354-360, (2016)
  • [5] Chen J, He S M, Huang B, Et al., Highly Space-Confined Ammonium Perchlorate in Three-Dimensional Hierarchically Ordered Porous Carbon with Improved Thermal Decomposition Properties, Applied Surface Science, 457, 1, pp. 508-515, (2018)
  • [6] 43, 2, (2020)
  • [7] Kohga M, Togo S., Influence of MnO<sub>2</sub> and Fe<sub>2</sub>O<sub>3</sub> on the Burning Characteristics of AN/AP Based Composite Propellants, Propellants, Explosives, Pyrotechnics, 45, pp. 141-146, (2020)
  • [8] Ma Z Y, Wu R J, Song J, Et al., Preparation and Characterization of Fe<sub>2</sub>O<sub>3</sub>/Ammonium Perchlorate(AP) Nanocomposites through Ceramic Membrane Anti-Solvent Crystallization, Propellants Explosives Pyrotechnics, 37, 2, pp. 183-190, (2012)
  • [9] Mahinroosta M., Catalytic Effect of Commercial Nano-CuO and Nano-Fe<sub>2</sub>O<sub>3</sub> on Thermal Decomposition of Ammonium Perchlorate, Journal of Nanostructure in Chemistry, 3, 1, pp. 1-6, (2013)
  • [10] 39, 1, (2016)