Preparation of Iron-modified Biochar and Its Application in Arsenic Contaminated Soil Remediation

被引:0
|
作者
Wei J. [1 ,2 ]
Liu Y.-H. [1 ,3 ,4 ]
Tu C. [3 ]
Deng S.-P. [1 ]
Hao D.-D. [3 ,4 ]
Xiao L. [2 ]
Mao M. [4 ]
机构
[1] State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing
[2] Guangdong Provincial Key Laboratory of Environmental Health and Land Resource, Zhaoqing University, Zhaoqing
[3] Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai
[4] College of Land Science and Technology, China Agricultural University, Beijing
来源
Huanjing Kexue/Environmental Science | 2023年 / 44卷 / 02期
关键词
adsorption mechanism; arsenic; biochar; iron-modified biochar; soil remediation;
D O I
10.13227/j.hjkx.202203011
中图分类号
学科分类号
摘要
Biochar has a range of advantages including large porosity, high specific surface area, and strong adsorption capacity. It has been widely used in environmental pollution remediation, soil improvement, and carbon sequestration and emission reduction. Arsenic (As) is a highly toxic pollutant widely distributed throughout the soil. In typical surface soils, the most common forms of As are arsenite (AsO33- ) and arsenate (AsO34- ). Since most biochar surfaces are negatively charged, the adsorption efficiency of biochar to arsenic is usually low, and the biochar material needs to be modified to enhance its As adsorption performance. Iron-based materials, such as zero valent iron and iron oxide, are excellent As adsorption materials with wide environmental sources. They can be loaded to biochar to form iron-modified biochar via precipitation, pyrolysis, ball-milling, and micro-biological methods. The combined advantages of the iron-modified biochar will expand the application of biochar materials in environmental remediation. Based on a systematic analysis of the literature on iron-modified biochar in recent years, this study reviewed the common preparation methods of iron-modified biochars; analyzed biochar substrates, iron-modified biochar, and their synergistic mechanisms on As adsorption; and briefly expounded the application status of iron-modified biochar in soil pollution remediation. The prospects of the future research direction of iron-modified biochar were put forward as a reference for the large-scale application of biochar materials in the future. © 2023 Science Press. All rights reserved.
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页码:965 / 974
页数:9
相关论文
共 85 条
  • [1] Ahmad M, Rajapaksha A U, Lim J E, Et al., Biochar as a sorbent for contaminant management in soil and water: a review, Chemosphere, 99, pp. 19-33, (2014)
  • [2] Xiao X, Chen B L, Chen Z M, Et al., Insight into multiple and multilevel structures of biochars and their potential environmental applications: a critical review, Environmental Science & Technology, 52, 9, pp. 5027-5047, (2018)
  • [3] Beesley L, Marmiroli M., The immobilisation and retention of soluble arsenic, cadmium and zinc by biochar, Environmental Pollution, 159, 2, pp. 474-480, (2011)
  • [4] Mukherjee A, Zimmerman A R, Harris W., Surface chemistry variations among a series of laboratory-produced biochars, Geoderma, 163, 3-4, pp. 247-255, (2011)
  • [5] Da Silva Medeiros D C C, Nzediegwu C, Benally C, Et al., Pristine and engineered biochar for the removal of contaminants co-existing in several types of industrial wastewaters: a critical review, Science of the Total Environment, 809, (2022)
  • [6] Bakshi S, Banik C, Rathke S J, Et al., Arsenic sorption on zero-valent iron-biochar complexes, Water Research, 137, pp. 153-163, (2018)
  • [7] Li S M, Harris S, Anandhi A, Et al., Predicting biochar properties and functions based on feedstock and pyrolysis temperature: A review and data syntheses, Journal of Cleaner Production, 215, pp. 890-902, (2019)
  • [8] Mohan D, Sarswat A, Ok Y S, Et al., Organic and inorganic contaminants removal from water with biochar, a renewable, low cost and sustainable adsorbent-a critical review, Bioresource Technology, 160, pp. 191-202, (2014)
  • [9] Haris M, Hamid Y, Usman M, Et al., Crop-residues derived biochar: synthesis, properties, characterization and application for the removal of trace elements in soils, Journal of Hazardous Materials, 416, (2021)
  • [10] Liu N, Wang L, Qiu H, Et al., Biochar catalyzed persulfate decoloration of azo dye acid orange 7, Journal of Jilin University (Earth Science Edition), 44, 6, pp. 2000-2009, (2014)