A study on effect of sol aging time on optical properties of zno thin films: Spectroscopic ellipsometry method

被引:0
作者
Aghkonbad E.M. [1 ]
Aghgonbad M.M. [1 ]
Sedghi H. [1 ]
机构
[1] Department of Physics, Faculty of Science, Urmia University, Urmia
来源
Micro and Nanosystems | 2019年 / 11卷 / 02期
关键词
Aging time; Annealing; Gap energy; Refractive index; Spectroscopic ellipsometry; Zinc oxide;
D O I
10.2174/1876402911666190313155304
中图分类号
学科分类号
摘要
Background: Due to wide band gap and large excitonic binding energy, being inexpensive, abundance in nature and easy synthesis ZnO is a promising candidate in many applications such as solar cells. Experimental: In the current work a series of ZnO thin films were deposited on glass substrates using sol-gel method to investigate the change in optical behavior of the film with sol aging time (asprepared, 8, 16, 24 and 32 hours) and the annealing temperature (300°C and 500°C). The optical properties of thin films were explored using spectroscopic ellipsometry method including the real and imaginary part of refractive index, real and imaginary part of dielectric function and band gap energy of the layers in the 300-900 nanometer wavelength range. Results: It can be deduced from the results that sol aging time and annealing temperature, affect the optical properties of the samples. Using single oscillator energy model of Wemple and Di Domenico parameters such as free charge carrier concentration ratio to effective mass, and plasma frequency, were calculated. Conclusion: The films prepared using 24 h aged solution, had the highest transmittance and the largest band gap energy. © 2019 Bentham Science Publishers.
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页码:100 / 108
页数:8
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  • [1] Toubane M., Tala-Ighil R., Bensouici F., Bououdina M., Cai W., Liu S., Souier M., Iratni A., Structural, optical and photocatalytic properties of ZnO nanorods: Effect of aging time and number of layers, Ceramics Int., 42, pp. 9673-9685, (2016)
  • [2] Godavarti U., Mote V.D., Dasari M., Role of cobalt doping on the electrical conductivity of ZnO nanoparticles, J. Asian Ceramic Soc., 5, 4, pp. 391-396, (2017)
  • [3] Chaitra U., Kekuda D., Rao K.M., Effect of annealing temperature on the evolution of structural, microstructural, and optical properties of spin coated ZnO thin films, Ceramics Int., 43, pp. 7115-7122, (2017)
  • [4] Bhardwaj V., Chowdhury R., Jayaganthan R., Nanomechanical and microstructural characterization of sputter deposited ZnO thin films, Appl. Surf. Sci., 389, pp. 1023-1032, (2016)
  • [5] Kumar M., Jeong H., Lee D., Sol-gel derived Hf- and Mg-doped high-performance ZnO thin film transistors, J. Alloy Compd., 720, pp. 230-238, (2017)
  • [6] Lee H., Zhang X., Hwang J., Park J., Morphological influence of solution-processed zinc oxide films on electrical characteristics of thin-film transistors, Materials, 9, (2016)
  • [7] Gencyilmaz O., Atay F., Akyuz I., Deposition and ellipsometric characterization of transparent conductive Al-doped ZnO for solar cell application, J. Clean Energ. Technol., 4, pp. 90-94, (2016)
  • [8] Sandeep K.M., Bhat S., Dharmaprakash S.M., Structural, optical, and LED characteristics of ZnO and Al doped ZnO thin films, J. Phys. Chem. Solid, 104, pp. 36-44, (2017)
  • [9] Musat V., Rego A.M., Monteiro R., Fortunato E., Microstructure and gas-sensing properties of sol-gel ZnO thin films, Thin Solid Films, 516, pp. 1512-1515, (2008)
  • [10] Rameshkumar C., Subalakshmi R., Structural, optical and electrical properties of ZnO: Al thin films synthesized by low cost spray pyrolysis for optoelectronic applications, J. Chem. Pharm. Res., 7, pp. 459-466, (2015)