Recent developments in the chemistry of metal oxopolyazides

被引：0
作者：
Haiges R. [1 ]
机构：
[1] Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, Los Angeles, 90089-1661, CA
来源：
Dalton Transactions | 2019年 / 48卷 / 03期
关键词：
50;
D O I：
10.1039/C8DT04258F
中图分类号：
学科分类号：
摘要：
The recent acomplished syntheses of novel metal oxopolyazides VO(N 3 ) 3 , NbO(N 3 ) 3 , NbO(N 3 ) 3 ·2CH 3 CN, MoO(N 3 ) 3 , MoO(N 3 ) 3 ·2CH 3 CN, WO(N 3 ) 4 , WO(N 3 ) 4 ·CH 3 CN, MoO 2 (N 3 ) 2 , MoO 2 (N 3 ) 2 ·2CH 3 CN, WO 2 (N 3 ) 2 , WO 2 (N 3 ) 2 ·2CH 3 CN and UO 2 (N 3 ) 2 ·CH 3 CN by the author is reviewed. The conversion of the compounds into 2,2′-bipyridine donor adducts and oxaazido metallates is discribed. The properties and X-ray crystal structures of the metal oxopolyazides are compared and discussed. © The Royal Society of Chemistry.
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页码：806 / 813
页数：7
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