Nonadiabatic, Relativistic, and Leading-Order QED Corrections for Rovibrational Intervals of He 4 2+ (X ς 2 u+)

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作者
Ferenc, Dávid [1 ]
Korobov, Vladimir I. [2 ]
Mátyus, Edit [1 ]
机构
[1] Institute of Chemistry, Elte, Eötvös Loránd University, Pázmány Péter sétány 1/A, Budapest,H-1117, Hungary
[2] Bogoliubov Laboratory of Theoretical Physics, Joint Institute for Nuclear Research, Dubna,141980, Russia
基金
欧盟地平线“2020”; 欧洲研究理事会; 俄罗斯基础研究基金会;
关键词
Ground state - Electrodynamics - Quantum theory;
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摘要
The rovibrational intervals of the He42+ molecular ion in its X ς2u+ ground electronic state are computed by including the nonadiabatic, relativistic, and leading-order quantum-electrodynamics corrections. Good agreement of theory and experiment is observed for the rotational excitation series of the vibrational ground state and the fundamental vibration. The lowest-energy rotational interval is computed to be 70.937 69(10) cm-1 in agreement with the most recently reported experimental value, 70.937 589(23)(60)sys cm-1 [L. Semeria et al., Phys. Rev. Lett. 124, 213001 (2020)PRLTAO0031-900710.1103/PhysRevLett.124.213001]. © 2020 American Physical Society.
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