Organic/inorganic hybrid polyimide matrix resins with high temperature resistance

被引：0

作者：

Liu Y. ^{[1
]}

Mo S. ^{[1
]}

Xu X. ^{[1
]}

Du X. ^{[1
,2
]}

He M. ^{[1
]}

Zhai L. ^{[1
]}

Fan L. ^{[1
,2
]}

机构：

[1] Key Laboratory of Science and Technology on High-Tech Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing

[2] School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing

来源：

Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica | 2023年 / 40卷 / 01期

关键词：

composite; matrix resin; organic/inorganic hybrid; polyimide; thermo-resistant mechanism;

D O I：

10.13801/j.cnki.fhclxb.20220415.002

中图分类号：

O63 [高分子化学（高聚物）]; TQ31 [高分子化合物工业（高聚物工业）];

学科分类号：

070305 ; 0805 ; 080501 ; 080502 ; 081704 ;

摘要：

Thermosetting polyimide resin matrix composites have been widely used in aerospace industry, but the heat resistance of traditional organic polyimide matrix resins is gradually insufficient to satisfy the design and application requirement of the aircrafts, with the development of aerospace technology. Therefore, novel organic/inorganic hybrid polyimides resistant to higher temperature have become the focus of research. In this paper, the recent progress of organic/inorganic hybrid polyimide matrix resins was summarized. The synthetic pathway, structure design, performance control, curing process and degradation behavior of polyhedral oligomeric silsesquioxane-containing polyimide, carborane-containing polyimide and siloxane-containing polyimide were reviewed, providing a detailed description of the characteristics and thermo-resistant mechanism of the organic/inorganic hybrid polyimide resins. The challenges and opportunities for the future development of organic/inorganic hybrid polyimide resins were also discussed and analyzed. © 2023 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.

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