Reduction in the Degree of Supercooling of the PCM D-mannitol Using Zeolite as a Nucleating Agent

被引:0
|
作者
Tang X. [1 ]
Ryu J. [1 ]
机构
[1] Graduate School of Engineering, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba-shi, Chiba
来源
Nihon Enerugi Gakkaishi/Journal of the Japan Institute of Energy | 2023年 / 102卷 / 04期
基金
日本科学技术振兴机构;
关键词
D-mannitol; Heterogeneous nucleation; PCM; Supercooling; Zeolite;
D O I
10.3775/jie.102.41
中图分类号
学科分类号
摘要
In this study, to alleviate the problem of low heat utilization efficiency caused by extreme supercooling of D-mannitol when used as a phase change material (PCM), we selected eight typical zeolites as nucleating agents and formed the corresponding D-mannitol-based PCMs through the melt blending method. The X-ray diffraction and Fourier transform infrared spectroscopy results reveal that no new compounds other than zeolite and D-mannitol were formed before and after melt blending, and the two were relatively chemically stable throughout the experiment, except for the composite PCM with“Zeolite HS-690 H-Mordenite.”Differential scanning calorimetry (DSC) analysis was used to investigate the effect of the addition of different types and quantities of zeolite on the crystallization behavior of D-mannitol. The results demonstrate that A- and mordenite crystal-type zeolites induce the crystallization of D-mannitol effectively, and the optimal mass ratio is approximately 10% mass fraction. This study provides long-term experimental data that will guide the practical application of PCMs. The results of the subsequent cyclic experiment reveal that the“Zeolite HS-690 H-Mordenite”additive caused the melting enthalpy of D-mannitol to decrease significantly, and the crystallization temperature also decreased over multiple cycles. In contrast, Zeolite HS-642 Sodium-Mordenite”demonstrated better enthalpy stability in the cyclic experiment than the two A crystal-type zeolites, with a decrease in melting enthalpy of only 1.0%. © 2023 Japan Institute of Energy. All rights reserved.
引用
收藏
页码:41 / 50
页数:9
相关论文
共 50 条
  • [21] Asymmetric oxyselenenylation of olefins using an optically active diaryl diselenide derived from D-mannitol
    Fujita, K
    Murata, K
    Iwaoka, M
    Tomoda, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 58 - ORGN
  • [22] Thermal behaviour of D-mannitol when used as PCM: Comparison of results obtained by DSC and in a thermal energy storage unit at pilot plant scale
    Gil, Antoni
    Barreneche, Camila
    Moreno, Pere
    Sole, Cristian
    Ines Fernandez, A.
    Cabeza, Luisa F.
    APPLIED ENERGY, 2013, 111 : 1107 - 1113
  • [23] DETERMINATION OF TITANIUM(IV) IN THE FORM OF D-MANNITOL AND D-SORBITOL COMPLEXES USING THE METHOD OF CIRCULAR-DICHROISM
    BELCHEVA, EK
    DUNINA, VV
    KULEV, II
    POTAPOV, VM
    JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1991, 46 (06): : 827 - 832
  • [24] ASYMMETRIC METHOXYSELENENYLATION OF OLEFINS USING AN OPTICALLY-ACTIVE DIARYL DISELENIDE DERIVED FROM D-MANNITOL
    FUJITA, K
    MURATA, K
    IWAOKA, M
    TOMODA, S
    TETRAHEDRON LETTERS, 1995, 36 (29) : 5219 - 5222
  • [25] Dielectric dispersion and hydrogen bonding interactions study of aqueous D-mannitol using time domain reflectometry
    Rander, D. N.
    Joshi, Yogesh S.
    Kanse, K. S.
    Kumbharkhane, A. C.
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2015, 53 (02) : 187 - 192
  • [26] Supercooling-dependent morphology evolution of an organic nucleating agent in poly(L-lactide)/poly(D-lactide) blends
    Shen, Sen-Qi
    Bao, Rui-Ying
    Liu, Zheng-Ying
    Yang, Wei
    Xie, Bang-Hu
    Yang, Ming-Bo
    CRYSTENGCOMM, 2017, 19 (12): : 1648 - 1657
  • [27] Experimental Investigation of Thermoelectric Power Generator Using D-Mannitol Phase Change Material for Transient Heat Recovery
    Jame, Lourdu
    Kumar, Joselin Retna
    Perumal, Suresh
    Jeyashree
    Moorthy, Manojkumar
    ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2021, 10 (06)
  • [28] Spin-on boron diffusion for n-type silicon wafers using borate esters of D-mannitol
    Sun, Xinjie i
    Zhao, Hua
    Yuan, Xiao
    Tong, Hua
    Yang, Yunxia
    MATERIALS RESEARCH EXPRESS, 2019, 6 (08):
  • [29] ASYMMETRIC INTRAMOLECULAR SELENOETHERIFICATION AND SELENOLACTONIZATION USING AN OPTICALLY-ACTIVE DIARYL DISELENIDE DERIVED FROM D-MANNITOL
    FUJITA, KI
    MURATA, K
    IWAOKA, M
    TOMODA, S
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) : 1641 - 1642
  • [30] Structural Transformations of D-Mannitol Induced by in Situ Milling Using Real Time Powder Synchrotron Radiation Diffraction
    Martinetto, Pauline
    Bordet, Pierre
    Descamps, Marc
    Dudognon, Emeline
    Pagnoux, William
    Willart, Jean-Francois
    CRYSTAL GROWTH & DESIGN, 2017, 17 (11) : 6111 - 6122