Evaluation of phase, morphological, optical and electrical properties of microwave synthesized Sn doped CdO nanostructures

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作者
Prakash, T. [1 ]
Kumar, E. Ranjith [1 ]
Gnanamoorthi, K. [2 ]
Munshi, Alaa M. [3 ]
Almehmadi, Samar J. [3 ]
Mersal, Gaber A.M. [4 ]
El Metwaly, Nashwa M. [3 ,5 ]
机构
[1] Department of Physics, KPR Institute of Engineering and Technology, Coimbatore,Tamil Nadu,641 407, India
[2] Department of Physics, Government Arts and Science College, Tirupattur,Tamil Nadu,635 901, India
[3] Department of Chemistry, Faculty of Applied Science, Umm-Al-Qura University, Makkah, Saudi Arabia
[4] Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif,21944, Saudi Arabia
[5] Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, Egypt
关键词
Morphology - Surface morphology - Nanostructures - Optical properties - Microwave irradiation - X ray diffraction - Fourier transform infrared spectroscopy - Chemical bonds - Energy gap - Crystallite size;
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摘要
Microwave irradiation was used to create Sn-(5%, 10%, and 15%) doped CdO nanostructures. XRD, FTIR, UV–vis spectra, SEM, EDX, and TEM were used to investigate structural, vibrational, surface morphological, and optical properties of CdO and Tin doped CdO nanostructures. The phase and structure of pure and Tin doped nanostructures are verified by the XRD profile. Debye Scherrer's method was used to measure the mean crystallite sizes of CdO and Tin doped CdO nanostructures. It shows that as the concentration of Sn doping increases, the crystallite size decreases. SEM was used to observe the impact of Tin doping on surface morphology. EDX confirms the existence of Sn, Cd, and O elements in all of the samples. The presence of chemical bonding in various nanostructures is confirmed by a Fourier transform infrared spectrum. With more Sn doping, the optical band gap varied from 1.94 to 1.69 eV. The electric measurement was carried out for all the samples using Hall setup and two probe methods. CdO doped with 10% of Sn samples exhibits better electrical property than the other samples. © 2021 Elsevier Ltd
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