Influence of Ions Distribution of Anion-Exchange Membranes on Diffusion Dialysis of Acid Recovery

被引：0

作者：

Li X. ^{[1
]}

Yue X. ^{[1
]}

Zhong S. ^{[1
]}

Zhou Y. ^{[1
]}

Liao S. ^{[1
]}

机构：

[1] School of Chemistry and Chemical Engineering, The Key Laboratory of Fuel Cell Technology of Guangdong Province, South China University of Technology, Guangzhou, 510640, Guangdong

来源：

Huanan Ligong Daxue Xuebao/Journal of South China University of Technology (Natural Science) | 2019年 / 47卷 / 05期

基金：

国家重点研发计划;

关键词：

Acid recovery; Anion exchange membrane; Diffusion dialysis; Ions distribution; Poly(arylene ether sulfone)s;

D O I：

10.12141/j.issn.1000-565X.180159

中图分类号：

学科分类号：

摘要：

In order to reveal the effects of ionic group structure and ions disctribution on the diffusion dialysis of anion exchange membranes(AEMs), three kinds of side-chain ionic poly(arylene ether)AEMs and a main-chain ionic poly(arylene ether)AEM were synthesized. Then, the four kinds of AEMs were characterized and evaluated in terms of structure, basic performances, acid stability, mechanical properties and diffusion dialysis performance. The results indicate that the symmetric side-chain ionic AEMs have better permeability selectivity and the main-chain ionic AEM has the best permeability selectivity owing to its symmetric ionic structure and dense aggregate structure, and that the basic performances, acid stability and mechanical properties of the AEMs all make clear that the prepared AEMs satisfy the basic acquirements of an diffusion dialysis process. Moreover, the experimental results of diffusion dialysis in simulated waste acid indicate that the prepared AEMs have better diffusion dialysis performances than those of the commerical TWDDA1, especially the main-chain ionic AEM, which wins the competition of diffusion dialysis at room temperature with an excellent proton diffusion coefficient of 0.025 m/h and a top separation factor of 42.49.All these mean that QMPAES has a great potential for acid recovery via diffusion dialysis. © 2019, Editorial Department, Journal of South China University of Technology. All right reserved.

引用

页码：9 / 17

页数：8

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