Synthesis and Properties of 3, 3'-Bis(2-nitroamino-1, 3, 4-oxadiazol-4-yl)-5, 5'-linked-1, 2, 4-oxadiazole and Its Energetic Salts

被引：0
|
作者：
Liao, Si-Cheng [1 ]
Deng, Mu-Cong [1 ]
Song, Si-Wei [1 ]
Jin, Yun-He [1 ]
Liu, Tian-Lin [1 ]
Zhang, Qing-Hua [1 ]
机构：
[1] Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang,621999, China
来源：
Hanneng Cailiao/Chinese Journal of Energetic Materials | 2020年 / 28卷 / 07期
关键词：
A new energetic compound 3; 3'-bis(2-nitroamino-1; 3; 4-oxadiazol-4-yl)-5; 5'-linked-1; 2; 4-oxadiazole (BNOBO) was synthesized starting from glyoxime through a five-step reaction. Based on the acidity of BNOBO; three energetic salts (5-7) were obtained through the reactions between BNOBO and aqueous ammonia; hydrazine and hydroxylamine; respectively. The structures of as-synthesized compounds were characterized by single-crystal X-ray diffraction; IR; NMR and element analysis. The crystal of BNOBO ammonium salt was obtained through solvent evaporation method; the obtained results show that it belongs to a monoclinic system and C2/c space group with a=12.7490(8) nm; b=9.5957(7); nm; c=18.5965(12); V=2272.1(3) nm3 and Z=4. Their thermal stability; density; detonation properties and sensitivity were evaluated by TG/DSC analysis; densitometer; EXPLO5 v6.02 software and BAM sensitivity tester; respectively. Among these new energetic compounds; BNOBO possesses the highest measured density of 1.90 g•cm-3 and the highest onset decomposition temperature of 215℃. The calculated detonation velocity and pressure of BNOBO are as high as 8789 m•s-1 and 32.7 GPa; respectively. These new energetic compounds also exhibit relatively low mechanical sensitivities; in which energetic salt 5 display the low impact sensitivity of more than 20 J and friction sensitivity of 220 N. © 2020; Editorial Board of Chinese Journal of Energetic Materials. All right reserved;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
引用
收藏
页码：632 / 637
相关论文
共 50 条
  • [31] Solvatochromic analysis and DFT computational study of N-(hexyl)-N-(5-(3-hydroxynaphthyl-2-yl)-1,3,4-oxadiazol-2-yl)amine
    Genc, Murat
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2019, 125 (06):
  • [32] Synthesis and Sulphonylation of 4-Amino-3-Methoxymethyl-5-(4-Chlorophenyl)-1H-Pyrazole
    Persidskaya, Diana, I
    Povarov, Ilya G.
    Efimov, Viktor V.
    Lyubyashkin, Alexey, V
    Suboch, Georgy A.
    Tovbis, Mikhail S.
    JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY, 2018, 11 (03): : 369 - 376
  • [33] Synthesis, antibacterial, antifungal and computational study of (E)-4-(3-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)-3-oxoprop-1-en-1-yl) benzonitrile
    Shinde, Rahul A.
    Adole, Vishnu A.
    Shinde, Rohit S.
    Desale, Bhatu S.
    Jagdale, Bapu S.
    RESULTS IN CHEMISTRY, 2022, 4
  • [34] Theoretical and Experimental Study on 3-Phenyl-5-Phenylazo-3H-[1,3,4] Thiadiazole-2-Thione
    Fangfang Jian
    Pusu Zhao
    Yuxia Hou
    Lude Lu
    Structural Chemistry, 2005, 16 : 123 - 128
  • [35] Theoretical and experimental study on 3-phenyl-5-phenylazo-3H-[1,3,4] thiadiazole-2-thione
    Jian, FF
    Zhao, P
    Hou, YX
    Lu, LD
    STRUCTURAL CHEMISTRY, 2005, 16 (02) : 123 - 128
  • [36] Synthesis, structural characterization, and DFT calculations of 3-buthyl-4-(3-methyl-3-mesitylcyclobut-1-yl)-1,3-thiazole-2(3H)-thione
    Sen, B.
    Barim, E.
    Kirilmis, C.
    Aygun, M.
    CRYSTALLOGRAPHY REPORTS, 2016, 61 (02) : 243 - 248
  • [37] Computational Study on the Chemical Structure, Explosive Properties and Sensitivity of N,N′-(1, 3, 4, 5, 7, 8-hexanitrooctahydro-diimidazo [4, 5-b: 4′, 5′-e]pyrazine-2, 6 (1H, 3H) -diylidene) dinitramide
    Wang Pengcheng
    Lu Ming
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2014, 35 (03): : 596 - 601
  • [38] Theoretical studies and spectroscopic characterization of novel 4-methyl-5-((5-phenyl-1,3,4-oxadiazol-2-yl)thio)benzene-1,2-diol
    Amiri, Somayeh Soleimani
    Makarem, Somayeh
    Ahmar, Hamid
    Ashenagar, Samaneh
    JOURNAL OF MOLECULAR STRUCTURE, 2016, 1119 : 18 - 24
  • [39] Synthesis, quantum chemical insights, vibrational spectral elucidation, insecticide likeness and docking analysis of the insecticide active novel molecule 2-(4-nitrophenyl)-(3,5-difluoro-pyridine-6-yl)-1,3,4-oxadiazole
    Karpagavalli, K.
    Magdaline, J. Daisy
    Chithambarathanu, T.
    Vijaya, P.
    SPECTROSCOPY LETTERS, 2025, 58 (03) : 282 - 300
  • [40] Synthesis, crystal structure, and thermal properties of energetic complex Cu (II) and Ag(I) based on 3-amino-4-(4,5-diamino-1,2,4-triazole-3yl)-furazan
    Ma, Huichao
    Zhang, Linan
    Qi, Yuan
    Liu, Shuliang
    Sun, Xiaoxia
    Huang, Jinhong
    Lu, Ming
    Lin, Qiuhan
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1321
12345