Study of CO2 Conversion in Boudouard Reaction Driven by Atmospheric-pressure Microwave Plasma Torch

被引：0
作者：
Li S. [1 ]
Wang X. [1 ]
Wu Y. [1 ]
机构：
[1] Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Ministry of Education, Department of Physics, Dalian University of Technology, Dalian
来源：
Gaodianya Jishu/High Voltage Engineering | 2024年 / 50卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Boudouard reaction; carbon dioxide(CO2); carbon monoxide(CO); conversion; microwave plasma;
D O I：
10.13336/j.1003-6520.hve.20230576
中图分类号：
学科分类号：
摘要：
An atmospheric-pressure microwave plasma torch(APMPT) is employed to drive Boudouard reaction to convert CO2 into CO for the purpose of resource utilization. The process of Boudouard reaction driven by APMPT is diagnosed by optical emission spectroscopy(OES) and the chemiluminescence occurrence is observed experimentally. The variation of CO concentration is measured with respect to the microwave power when the graphite rod is placed in the downstream of the afterglow of CO2 APMPT by means of gas chromatograph(GC). Furthermore, a hollow graphite rod is proposed, thereby the conversion rate is enhanced, and the variation of conversion with the microwave power, gas flow rate, geometric sizes of rod, and composition of working gas is investigated. Furthermore, the conversion effects by Boudouard reaction with use of various carbon materials are compared and the discussion of mechanism is delivered. The experimental results indicate that the Boudouard reaction occurring on the surface of graphite rod plays the pivotal role in CO2 conversion into CO, and the concentration of the generated CO increases with diameter of the hollow graphite rod; meanwhile, the addition of Ar or N2 into carrier gas CO2, respectively,will improve the CO concentration. © 2024 Science Press. All rights reserved.
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页码：414 / 422
页数：8
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