Effect of Defects on Performance of All Inorganic Perovskite Solar Cells

被引：0

作者：

Yao G. ^{[1
]}

Wen C. ^{[1
,2
]}

Liu J. ^{[1
,3
]}

Su Z. ^{[1
]}

机构：

[1] Fujian Key Laboratory for Advanced Micro-nano Photonics Technology and Devices, College of Physics and Information Engineering, Quanzhou Normal University, Quanzhou

[2] School of Advanced Manufacturing, Fuzhou University, Quanzhou

[3] College of Photonic and Electronic Engineering, Fujian Normal University, Fuzhou

来源：

Faguang Xuebao/Chinese Journal of Luminescence | 2023年 / 44卷 / 11期

关键词：

all inorganic; defect; simulation; perovskite solar cell;

D O I：

10.37188/CJL.20230196

中图分类号：

学科分类号：

摘要：

The effects of defects on the performance of all inorganic perovskite solar cells was studied using a one-dimensional solar cell simulation software SCAPS. It is found that in the device ITO/SnO2/CsPbI3/CuI/Au，the density of the defects at the CuI/CsPbI3 interface and in the CsPbI3 photoactive layer has dramatically influence on the performance of the device. With the increase of the defect density，the open-circuit voltage，short-circuit current，filling factor，and power conversion efficiency of the device all decrease，especially when the defect density exceeds 1015 cm-3. On the contrary，the defects at the CsPbI3/SnO2 interface have almost no effect on device performance. By optimizing the defect density of the device，the thickness and doping concentration of the photoactive layer，a power conversion efficiency higher than 20% can be obtained in the all inorganic perovskite solar cells. © 2023 Chines Academy of Sciences. All rights reserved.

引用

页码：2033 / 2040

页数：7

共 43 条

[1]

KOJIMA A, TESHIMA K, Et al., Organometal halide perovskites as visible-light sensitizers for photovoltaic cells［J］, J. Am. Chem. Soc, 131, 17, pp. 6050-6051, (2009)

[2]

ZHAO Y，MA F, Et al., Inactive（PbI2）2RbCl stabilizes perovskite films for efficient solar cells［J］, Science, 377, 6605, pp. 531-534, (2022)

[3]

YOO J J，, SEO G, CHUA M R，, Et al., Efficient perovskite solar cells via improved carrier management［J］, Nature, 590, 7847, pp. 587-593, (2021)

[4]

JEONG J，, KIM M，, SEO J，, Et al., Pseudo-halide anion engineering for α -FAPbI3 perovskite solar cells［J］, Nature, 592, 7854, pp. 381-385, (2021)

[5]

LI Z, Et al., Organometallic-functionalized interfaces for highly efficient inverted perovskite solar cells［J］, Science, 376, 6591, pp. 416-420, (2022)

[6]

MIN H, LEE D Y，, KIM J，, Et al., Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes［J］, Na⁃ ture, 598, 7881, pp. 444-450, (2021)

[7]

JIANG Q, TONG J H, XIAN Y M，, Et al., Surface reaction for efficient and stable inverted perovskite solar cells［J］, Na⁃ ture, 611, 7935, pp. 278-283, (2022)

[8]

Interactive best research-cell efficiency chart［EB/OL］

[9]

WANG R, MUJAHID M, DUAN Y，, Et al., A review of perovskites solar cell stability［J］, Adv. Funct. Mater, 29, 47, (2019)

[10]

LEE S Y，, LEE J H，, Et al., Stabilization of perovskite solar cells：recent developments and future perspectives ［J］, Adv. Mater, 34, 50, (2022)

← 1 2 3 4 5 →