Preparation and thermochromic behavior of low-temperature thermochromic microcapsule temperature indicators

被引：12
作者：
Pu Y. [1 ]
Fang J. [1 ]
机构：
[1] Key Laboratory of Wood Material Science and Application, Ministry of Education, Beijing Forestry University, Beijing
来源：
Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2022年 / 653卷
关键词：
Food packaging; Leuco dyes; Low-temperature thermochromic materials; Methyl laurate; Microcapsules; Temperature indicators;
D O I：
10.1016/j.colsurfa.2022.129889
中图分类号：
学科分类号：
摘要：
Studies have rarely investigated thermochromic materials at refrigeration temperatures (about 8 °C). In this study, such a temperature indicator that can change color at refrigerated temperature was synthesized. Crystal violet lactone (CVL) and lauryl gallate (LG) were dissolved in methyl laurate (ML) at a phase change temperature of 7 °C. A series of low-temperature reversible thermochromic leuco dyes were obtained and used to prepare low-temperature reversible thermochromic microcapsule (TCM) temperature indicators. The FTIR results show that the thermochromic behavior of TCM temperature indicator was determined by LG controlling CVL to open and close the ring for reversible conversion between the lactone structure (colorless) and conjugated structure (colored). The effects of the mass ratio of the three components (wCVL:wLG:wML) on the thermochromic behavior were analyzed according to the CIE Lab chromaticity indexes. The total thermochromic color difference between leuco dye and TCM temperature indicator reached the maximum when the wCVL:wLG:wML was 1:3:125. The TCM temperature indicator gradually changed from dark blue to white from 1 °C to 8 °C. The DSC results show that the decolorization temperature of TCM temperature indicator was very close to the melting point of ML. In addition, microencapsulation prevented the phase separation of leuco dyes and improved the stability of thermochromic materials. The results indicate the enormous potential of TCM temperature indicator for studying thermochromic materials at low temperatures and in temperature monitoring of refrigerated food packages. © 2022
引用
收藏
相关论文
共 16 条
  • [1] Kulcar R., Friskovec M., Hauptman N., Vesel A., Gunde M.K., Colorimetric properties of reversible thermochromic printing inks, Dyes Pigments, 86, pp. 271-277, (2010)
  • [2] Kim I.J., Ramalingam M., Son Y.-A., Investigation of reversible self-thermochromism in microencapsulated fluoran-based materials, Dyes Pigments, 151, pp. 64-74, (2018)
  • [3] Panak O., Drzkova M., Kaplanova M., Novak U., Klanjsek Gunde M., The relation between colour and structural changes in thermochromic systems comprising crystal violet lactone, bisphenol A, and tetradecanol, Dyes Pigments, 136, pp. 382-389, (2017)
  • [4] Tozum M.S., Alay Aksoy S., Alkan C., Manufacturing surface active shell and bisphenol A free thermochromic acrylic microcapsules for textile applications, Int. J. Energy Res., 45, pp. 7018-7037, (2020)
  • [5] Tozum M.S., Aksoy S.A., Alkan C., Microencapsulation of three-component thermochromic system for reversible color change and thermal energy storage, Fibers Polym., 19, pp. 660-669, (2018)
  • [6] Wang S., Yi L., Fang Y., Wang L., Yao J., Marek J., Zhang M., Reversibly thermochromic and high strength core‐shell nanofibers fabricated by melt coaxial electrospinning, J. Appl. Polym. Sci., 138, (2021)
  • [7] Geng X., Li W., Wang Y., Lu J., Wang J., Wang N., Li J., Zhang X., Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing, Appl. Energy, 217, pp. 281-294, (2018)
  • [8] Geng X., Li W., Yin Q., Wang Y., Han N., Wang N., Bian J., Wang J., Zhang X., Design and fabrication of reversible thermochromic microencapsulated phase change materials for thermal energy storage and its antibacterial activity, Energy, 159, pp. 857-869, (2018)
  • [9] Tozum M.S., Alkan C., Aksoy S.A., Developing of thermal energy storing visual textile temperature indicators based on reversible color change, J. Ind. Text., (2020)
  • [10] Bourque A.N., White M.A., Control of thermochromic behaviour in crystal violet lactone (CVL)/alkyl gallate/alcohol ternary mixtures, Can. J. Chem., 93, pp. 22-31, (2015)
12