Synthesis and structural characterisation of some 1:1:2 complexes of silver(I) compounds with triphenylpnictides and “ethylenediamine”, [(Ph3E)(N-en)Ag(N-en-N')2Ag(N-en)(EPh3)]2+(X−)2

被引：0

作者：

Effendy ^{[1
,2
]}

Marchetti F. ^{[3
]}

Di Nicola C. ^{[3
]}

Pettinari C. ^{[4
,5
]}

Pettinari R. ^{[5
]}

Skelton B.W. ^{[2
]}

Tombesi A. ^{[4
]}

White A.H. ^{[2
]}

机构：

[1] Jurusan Kimia, FMIPA Universitas Negeri Malang, Jalan Surabaya 6, Malang

[2] School of Molecular Sciences, University of Western Australia, Perth, 6009, WA

[3] School of Science and Technology, Università degli Studi di Camerino, via S. Agostino 1, Camerino, 62032, MC

[4] School of Pharmacy, Università degli Studi di Camerino, via S. Agostino 1, Camerino, 62032, MC

[5] Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano, Sesto Fiorentino

来源：

Inorganica Chimica Acta | 2022年 / 534卷

关键词：

1,2-diaminoethane; Dinuclear compounds; Silver; Triphenylpnictides; X-ray;

D O I：

10.1016/j.ica.2022.120825

中图分类号：

学科分类号：

摘要：

Colourless crystalline adducts obtained by the crystallization of various silver(I) compounds in 1:1 M proportions with EPh3 (E = P, As, Sb) from 1,2-diaminoethane (ethylenediamine) (en ≡ H2N(CH2)2NH2) have been structurally characterized by room temperature single crystal X-ray studies as 1:1:2 AgX: EPh3: en adducts. The array of compounds is isomorphous, triclinic, P1¯, a ~ 8.5, b ~ 9.2, c ~ 16.9 Å, α ~ 86.6, β ~ 80, γ ~ 65.5°, Z = 1 dimer, being ionic [(Ph2E)(N-en)Ag(N-en-N')2Ag(N-en)(EPh3)]2+(X−)2, with binuclear centrosymmetric cations containing four-coordinate silver; the nitrogen component of the latter N3AgE array is made up of a pair of N from two bridging en groups and, remarkably, one N from unidentate N-en. Compounds have been spectroscopically and structurally characterized for E = P, X = Cl, Br; E = As, X = Cl, Br; E = Sb, X = Cl, Br, NO3. Bond distances and angles are compared with previous report on literature for AgX: en adducts. © 2022

引用

共 37 条

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