Chemically reduced silver nanoparticles: preparation and applications

被引:2
作者
Tan, Da-Qing [1 ]
Dong, Meng-Yao [1 ]
Xia, Yi-jie [2 ]
Wang, Xuan-Ye [2 ]
Wei, Hui-Ge [2 ]
机构
[1] Chongqing Ind Polytech Coll, Sch Mech Engn & Automat, Key Lab Mat Proc & Mold Technol, Chongqing, Peoples R China
[2] Tianjin Univ Sci & Technol, Coll Chem Engn & Mat Sci, Tianjin Key Lab Brine Chem Engn & Resource Ecoutl, Tianjin, Peoples R China
关键词
material chemistry; nanoparticles; sensors; GLUCOSE; NANOPRISMS; CATALYSTS; GROWTH; NANOSPHERES; PALLADIUM; MECHANISM; OXIDATION; ELECTRODE; EFFICACY;
D O I
10.1680/jemmr.23.00064
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
By virtue of their unique physiochemical properties, silver nanoparticles (AgNPs) have attracted enormous research interest for versatile applications. It is critical to study the effect of the microstructure - for example, the shape and the size of AgNPs - on their performance. Herein, AgNPs with varying shapes and sizes were synthesized by varying the manner that the reducing agent sodium borohydride (NaBH4) was added (i.e. multistep and one-step reduction methods) and then were studied for photocatalysis of dyes and electrocatalytic oxidation of glucose. The results showed that triangular AgNPs, spherical AgNPs or a mixture of triangular- and spherical-shaped AgNPs was obtained from the multistep reduction method, whereas only spherical-shaped AgNPs were yielded from the one-step reduction method. The sizes could be manipulated by changing the concentrations of the reagents or the reaction temperature. The triangular-shaped and smaller-sized AgNPs were more effective for photocatalysis of dyes, and the degradation percentage of methylene blue was enhanced to 95% for the silver (Ag)-titanium dioxide (TiO2) complex from 50% for pure titanium dioxide. Moreover, the spherical-shaped AgNPs with a smaller size could effectively detect glucose at a very low concentration of 5-10mM with an excellent glucose tolerance.
引用
收藏
页码:56 / 64
页数:9
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